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Deviations from eutectic-forming element criteria in the Al-Co-Cr-Fe-Ni system
Department of Materials Science and Metallurgical Engineering, Indian Institute of Technology Hyderabad, Kandi (IND); Department of Metallurgical Engineering and Materials Science, Indian Institute of Technology Indore, Khandwa Road, Simrol (IND).ORCID iD: /0000-0002-4992-770X
University West, Department of Engineering Science, Division of mechanical engineering. (KAMPT)ORCID iD: 0000-0001-6966-7717
Department of Metallurgical Engineering and Materials Science, Indian Institute of Technology Indore, Khandwa Road, Simrol (IND).
Advanced Magnetics Group, Defence Metallurgical Research Laboratory, Kanchanbagh, Hyderabad (IND).
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2025 (English)In: Materials letters (General ed.), ISSN 0167-577X, E-ISSN 1873-4979, Vol. 384, article id 138126Article in journal (Refereed) Published
Abstract [en]

Identifying eutectic compositions in multi-principal element alloys (MPEAs) is challenging in the absence of higher-order phase diagrams. The present study addresses this issue by proposing a revised criterion for eutectic-forming elements (EFEs), allowing elements to qualify as EFEs regardless of their binary eutectic-forming ability or enthalpy of mixing rank with other elements in the alloy system considered. Using this criterion, CALPHAD simulations in the Al-Co-Fe-Ni system identified a eutectic composition with Co as the EFE. Experimental validation confirmed that this composition exhibits a stable two-phase FCC plus BCC eutectic structure. This approach expands the design space for eutectic MPEAs, offering the potential for identifying new compositions.

Place, publisher, year, edition, pages
2025. Vol. 384, article id 138126
Keywords [en]
CALPHAD, Eutectic multi-principal element alloys, Eutectic-forming element
National Category
Metallurgy and Metallic Materials Applied Mechanics
Research subject
Production Technology
Identifiers
URN: urn:nbn:se:hv:diva-23045DOI: 10.1016/j.matlet.2025.138126ISI: 001420673400001Scopus ID: 2-s2.0-85215995270OAI: oai:DiVA.org:hv-23045DiVA, id: diva2:1943097
Available from: 2025-03-07 Created: 2025-03-07 Last updated: 2025-12-23Bibliographically approved

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Loganathan, Naveen

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