Hardfacing is commonly used in parts recovery and in obtaining surfaces with improved properties. Within this field, it is important to analyze the effect of alloying elements on the properties of the deposited layers. One of the critical parameters affecting alloying performances in SMAW is improper arc length. This article examines the effect of the addition of niobium in different quantities (0, 2, 4, 6, and 8% by weight) to the electrode coating in Fe-Cr-C shielded metal arc welding (SMAW), with short and long arc lengths, on the operational process efficiency, dilution, arc energy, microstructure, and microhardness of the deposited layers. A decrease in operational process efficiency and dilution was found with increases in niobium content. On the other hand, it was found that adding niobium leads to a refinement in chromium carbide sizes, directly affecting the hardness of the obtained deposits. There is a direct relationship between the arc energy, with both short and long arc lengths, leading to a tendency to decrease the dilution in the obtained hardfacing.