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Hot Cracking Susceptibility in Austenitic High-Temperature Alloys
Högskolan Väst, Institutionen för ingenjörsvetenskap, Avdelningen för maskinteknik. (KAMPT)ORCID-id: 0000-0001-7880-6002
2026 (Engelska)Licentiatavhandling, sammanläggning (Övrigt vetenskapligt)
Abstract [en]

Manufacturing thermal power plants requires welding of high-temperature alloys such as stainless steels and Ni-based alloys. These alloys are sensitive to hot cracking during welding, mainly due to their FCC-microstructure, especially in multipass welding of thick sections where thermal stresses increase. This work evaluates the hot cracking susceptibility of Sanicro® 25 and 310S stainless steels, as well as all-weld metal produced with Ni-based filler metals Alloy 617 and Alloy 617mod., commonly used for welding Sanicro® 25. The aim of this thesis is therefore to improve understanding of cracking susceptibility in high-temperature stainless steels and Ni-based alloys for thermal power plant applications. Varestraint weldability testing was used to rank and assess hot cracking susceptibility under controlled conditions.

Additional testing and examination included metallography, mechanical testing and the use of computational thermodynamics. Results show that Sanicro® 25 is slightly more susceptible to hot cracking than 310S, while both Alloy 617 all-weld metals were less susceptible than Sanicro® 25. The higher cracking susceptibility correlates with a larger fraction of phases and precipitates in or close to the cracks in the microstructure, which was also consistent with thermodynamic calculations. These calculations revealed a narrower solidification interval for 310S compared to Sanicro® 25, and higher a fraction of precipitated phases for Alloy 617 than Alloy 617mod. Overall, it is concluded that Sanicro® 25 remains as a good candidate material for thermal power plants and that today’s recommended filler metal Alloy 617, and in particular the Alloy 617mod. version, is less susceptible to hot cracking than Sanicro® 25. Thus, based on the hot cracking susceptibility, Sanicro® 25 material can be assessed for welded thermal power plant applications based on the parent materials inherent properties and the weldment will not be the weakest part. 

Abstract [sv]

Värmekraftverk kräver användning av högtemperaturbeständiga metalliska material vilka är utvecklade för att fungera vid de högre temperaturerna som uppstår under drift i ett värmekraftverk. I dessa värmekraftverk används rostfria stål och Ni-baserade legeringar, vilka är känsliga för en viss typ av defekt kallad ”varmsprickor” som kan uppstå vid svetsning av materialet, som i svetsoperationen kommer att smälta och åter stelna. Varmsprickorna påverkas negativt av spänningar som uppstår i materialet på grund av svetsning, vilka kommer att öka desto tjockare material som svetsas, då flera lager av svetsning krävs vid ökad materialtjocklek.  

I detta arbete så utvärderas känsligheten för varmsprickbilning hos de rostfria stålen Sanicro® 25 och 310S samt för svetsgods tillverkat med det Ni-baserade tillsatsmaterialen Alloy 617 och Alloy 617mod., vilka vanligtvis används för svetsning av Sanicro® 25. Målet har varit att förbättra förståelsen för varmsprickkänsligheten hos dessa högtemperaturmaterial för tillämpningar i värmekraftverk. För att för att rangordna och bedöma legeringarnas varmsprickkänslighet under kontrollerade förhållanden användes så kallad Varestraintprovning, som innebär att material får stelna samtidigt som det böjs. Dessutom användes mikroskopiska undersökningar samt beräkningsmetoder för att bättre förstå resultaten från Varestraintprovningen. 

Resultaten visar att Sanicro® 25 är något mer känsligt för varmsprickbildning än 310S. Däremot konstaterades att båda Alloy 617-svetsgodsen var mindre känsliga än Sanicro® 25, vilket indikerar att tillsatsmaterialet inte är den svaga länken ur ett varmsprickperspektiv och därmed ett möjligt alternativ för applikationer i värmekraftverk.

Ort, förlag, år, upplaga, sidor
Trollhättan: University West , 2026. , s. 66
Serie
Licentiate Thesis: University West ; 59
Nyckelord [en]
Varestraint testing; Hot cracking; Weldability; Sanicro® 25; 310S; Alloy 617; Stainless steel; Ni-based alloys
Nyckelord [sv]
Varestraintprovning; Varmsprickor; Svetsbarhet; Sanicro® 25; 310S; Alloy 617; Rostfria stål; Ni-baserade legeringar
Nationell ämneskategori
Bearbetnings-, yt- och fogningsteknik Metallurgi och metalliska material
Forskningsämne
Produktionsteknik
Identifikatorer
URN: urn:nbn:se:hv:diva-25030ISBN: 978-91-89969-66-7 (tryckt)ISBN: 978-91-89969-65-0 (digital)OAI: oai:DiVA.org:hv-25030DiVA, id: diva2:2050245
Presentation
2026-05-11, J106, Gustava Melins gata, Trollhättan, 13:00 (Engelska)
Opponent
Handledare
Anmärkning

Paper C is accepted for publication in the licentiate thesis. After printing, paper C has been published and is also available as a partial work here.

Tillgänglig från: 2026-05-11 Skapad: 2026-04-01 Senast uppdaterad: 2026-05-18
Delarbeten
1. Evaluation of test results and ranking criteria for Varestraint testing of an austenitic high-temperature alloy
Öppna denna publikation i ny flik eller fönster >>Evaluation of test results and ranking criteria for Varestraint testing of an austenitic high-temperature alloy
2020 (Engelska)Ingår i: Welding in the World, ISSN 0043-2288, E-ISSN 1878-6669, Vol. 64, s. 903-912Artikel i tidskrift (Refereegranskat) Published
Abstract [en]

Varestraint testing is commonly used to evaluate hot cracking susceptibility of materials. In this paper, the dependence of operators and evaluation technique on test results is studied for a high-temperature austenitic stainless steel (UNS S31035). Samples were tested at six different strain levels ranging from 0.7 to 3.8%. Four different operators evaluated the same samples following the same instructions on how to measure the cracks manually in an optical microscope at x 25 magnification. The largest variation among operators evaluation was found for low strain levels where small and few cracks were found. In addition, one of the four operators used image analysis to evaluate the samples at x 50 magnification. The average total crack length and total number of cracks in fusion zone and heat-affected zone were approximately 1.5 times higher when using image analysis compared with manual evaluation. Image analysis at x 50 made it possible to detect smaller cracks compared with manual evaluation at x 25 magnification, contributing to an increased number of cracks detected. The maximum crack length using image analysis at x 50 was similar to manual evaluation made at x 25 magnification and was the criterion that showed the least variation in this study. However, further comparisons using other magnifications are needed to verify the agreement between manual evaluation and image analysis found in this study. An advantage with evaluation using image analysis is that it provides traceable results. A harmonized standard for Varestraint testing, and especially for evaluation, would decrease the variation among operators and laboratories.

Nyckelord
Varestraint testing; High-temperature austenitic stainless steel; Hot crack evaluation; Ranking criteria
Nationell ämneskategori
Bearbetnings-, yt- och fogningsteknik
Identifikatorer
urn:nbn:se:hv:diva-15119 (URN)10.1007/s40194-020-00891-6 (DOI)000522945300001 ()2-s2.0-85083270874 (Scopus ID)
Forskningsfinansiär
KK-stiftelsen
Tillgänglig från: 2020-04-16 Skapad: 2020-04-16 Senast uppdaterad: 2026-04-01
2. Varestraint weldability testing of Sanicro 25 and 310S stainless steel
Öppna denna publikation i ny flik eller fönster >>Varestraint weldability testing of Sanicro 25 and 310S stainless steel
2022 (Engelska)Ingår i: Advances in Welding & Additive Manufacturing Research / [ed] Stan A. David,Zhili Feng, Thoams J. Lienert, American Welding Society , 2022Konferensbidrag, Publicerat paper (Refereegranskat)
Abstract [en]

Sandvik Sanicro 25 (UNS S31035) is an advanced high temperature austenitic stainless steel that potentially can be used in super-heaters and reheaters in the next generation of advanced ultra-super critical power plants (A-USC). The material possesses both high creep strength and good corrosion resistance at temperatures up to 700°C. It is, however, well known that an austenitic solidification mode combined with a fully austenitic microstructure exacerbate susceptibility towards hot cracking. In this paper, the Varestraint test is used to investigate the susceptibility to hot cracking of Sanicro 25 and is compared to the well-known grade 310S (UNS S31008), which has been used in past generations of power plants. This investigation therefore attempts, based on the Varestraint weldability test, microstructural inspection, and thermodynamical calculations, to investigate if there are any differences in cracking mechanisms between these two grades due to the additional alloying elements used in Sanicro 25. The results show that the hot cracking susceptibility of Sanicro 25 is only slightly higher than that of 310S. The larger solidification interval for Sanicro 25 compared to 310S predicted by computational thermodynamics and the niobium-enriched phases in the grain boundaries of Sanicro 25 supported the hot cracking susceptibility results. Weldability of the two alloys is therefore judged to be comparable making the newer alloy a good candidate material to be used in A-USC power plants from a weldability perspective.

Ort, förlag, år, upplaga, sidor
American Welding Society, 2022
Nyckelord
varestraint weldability, stainless steel.
Nationell ämneskategori
Bearbetnings-, yt- och fogningsteknik
Forskningsämne
Produktionsteknik
Identifikatorer
urn:nbn:se:hv:diva-19967 (URN)
Konferens
Advances in Welding & Additive Manufacturing Research Virtual Conference 2022, June 13,2 2022 - June 16, 2022
Anmärkning

The conference organizer has given permission to publish the conference paper in full text.

Tillgänglig från: 2023-05-11 Skapad: 2023-05-11 Senast uppdaterad: 2026-04-30Bibliografiskt granskad
3. Hot cracking susceptibility of alloy 617 and modified alloy 617 weld metals
Öppna denna publikation i ny flik eller fönster >>Hot cracking susceptibility of alloy 617 and modified alloy 617 weld metals
2026 (Engelska)Ingår i: Welding International, ISSN 0950-7116, s. 1-14Artikel i tidskrift (Refereegranskat) Published
Abstract [en]

Two 617-type filler metals with different Carbon and Boron contents were used to deposit TIG all-weld metal. Longitudinal Varestraint testing was utilized to evaluate and compare their weld metal cracking susceptibility. Hardness, tensile, and impact toughness testing were conducted on the all-weld metal samples, and light optical microscopy as well as scanning electron microscopy, equipped with energy dispersive spectroscopy were adopted for the microstructural inspection of the Varestraint tested samples. Computational thermodynamics supported in calculating the solidification interval and predicting the phases formed. Results showed that the modified Alloy 617 (617mod.) with higher Boron and lower Carbon content is the preferred filler metal, because it showed lower hot cracking susceptibility than the regular version of Alloy 617. In addition, the impact toughness of the modified Alloy 617 was almost three times higher than for Alloy 617 but showed lower tensile strength. In terms of microstructure, the modified Alloy 617 disclosed less precipitates along the cracks than the regular Alloy 617. These observations were supported by computational thermodynamic calculations.

Ort, förlag, år, upplaga, sidor
Taylor & Francis, 2026
Nyckelord
varestraint, hot cracking, nickel-base
Nationell ämneskategori
Bearbetnings-, yt- och fogningsteknik Metallurgi och metalliska material
Forskningsämne
Produktionsteknik
Identifikatorer
urn:nbn:se:hv:diva-25133 (URN)10.1080/09507116.2026.2644270 (DOI)
Anmärkning

CC-BY 4.0

Funding for this work was provided by Alleima EMEA AB as well as the research school Smart Industry Sweden via the KK-Foundation in Sweden. Stiftelsen för Kunskaps- och Kompetensutveckling (SiCoMaP; SMART Industry Sweden).

Tillgänglig från: 2026-04-30 Skapad: 2026-04-30 Senast uppdaterad: 2026-05-18

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