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  • 1.
    Abou Nada, Fahed
    et al.
    Lund University, Department of Physics, Division of Combustion Physics, Box 118, Lund, Swede.
    Lantz, Andreas
    Siemens Industrial Turbomachinery AB, Finspång, Sweden.
    Larfeldt, Jenny
    Siemens Industrial Turbomachinery AB, Finspång, Sweden.
    Markocsan, Nicolaie
    University West, Department of Engineering Science, Division of Subtractive and Additive Manufacturing.
    Alden, Marcus
    Lund University, Department of Physics, Division of Combustion Physics, Box 118, Lund, Swede.
    Richter, Mattias
    Lund University, Department of Physics, Division of Combustion Physics, Box 118, Lund, Swede.
    Remote temperature sensing on and beneath atmospheric plasma sprayed thermal barrier coatings using thermographic phosphors2016In: Surface & Coatings Technology, ISSN 0257-8972, E-ISSN 1879-3347, Vol. 302, p. 359-367Article in journal (Refereed)
    Abstract [en]

    Investigations on remote temperature sensing of yttria stabilized zirconia (YSZ) thermal barrier coatings (TBCs) at the surface and at the bond-coat/top-coat interface were carried out. Using Y2O3:Eu thermographic phosphor as an embedded temperature sensing layer, sub-surface temperature probing through 300 mu m of atmospheric plasma sprayed YSZ is demonstrated. The Y2O3:Eu thermographic phosphor displays a temperature sensitivity ranging between 400 degrees C up to a maximum of 900 degrees C when utilizing the luminescence originating from the 611 nm emission band. Dysprosium stabilized zirconia (10 wt.% DySZ), a TBC material, is also investigated and established as a temperature sensor from 400 degrees C up to a temperature of 1000 degrees C using both the intensity decay time and emission intensity ratio methods. In addition, the luminescence of presumed optically inactive YSZ materials was spectroscopically investigated in terms of optical interferences caused by impurities. A validation temperature probing measurement through 300 mu m of YSZ top-coat was successfully performed in a SGT-800 Siemens burner running at six different operating conditions in an atmospheric combustion rig. (C) 2016 Elsevier B.V. All rights reserved.

  • 2.
    Battabyal, Manjusha
    et al.
    Chalmers University of Technology.
    Klement, Uta
    Chalmers University of Technology.
    Norell, Mats
    Chalmers University of Technology.
    Goutier, Simon
    University of Limoges.
    Markocsan, Nicolaie
    University West, Department of Engineering Science, Division of Production Engineering.
    Comparison of microstructure in Ni-Al single splats and millimeter sized droplets2011In: Surface Modification Technologies XXV : Proceedings of the Twenty Fith International Conference on Surface Modification Technologies - SMT25: Trolhättan June 20-22, 2011, 2011, p. 3-12Conference paper (Refereed)
  • 3.
    Bolelli, G.
    et al.
    University of Modena and Reggio Emilia, Dipartimento di Ingegneria “Enzo Ferrari”, Via Pietro Vivarelli 10/1, I-41125 Modena (MO), Italy.
    Berger, L. -M
    Fraunhofer-Institut für Werkstoff- und Strahltechnik (IWS), Winterbergstr. 28, D-01277 Dresden, Germany.
    Börner, T.
    University of Modena and Reggio Emilia, Dipartimento di Ingegneria “Enzo Ferrari”, Via Pietro Vivarelli 10/1, I-41125 Modena (MO), Italy.
    Koivuluoto, H.
    Tampere University of Technology, Department of Materials Science, Korkeakoulunkatu 6, FI-33720 Tampere, Finland.
    Lusvarghi, L.
    University of Modena and Reggio Emilia, Dipartimento di Ingegneria “Enzo Ferrari”, Via Pietro Vivarelli 10/1, I-41125 Modena (MO), Italy.
    Lyphout, Christophe
    University West, Department of Engineering Science, Division of Production Engineering.
    Markocsan, Nicolaie
    University West, Department of Engineering Science, Division of Production Engineering.
    Matikainen, V.
    Tampere University of Technology, Department of Materials Science, Korkeakoulunkatu 6, FI-33720 Tampere, Finland.
    Nylén, Per
    University West, Department of Engineering Science, Division of Production Engineering.
    Sassatelli, P.
    University of Modena and Reggio Emilia, Dipartimento di Ingegneria “Enzo Ferrari”, Via Pietro Vivarelli 10/1, I-41125 Modena (MO), Italy.
    Trache, R.
    Fraunhofer-Institut für Werkstoff- und Strahltechnik (IWS), Winterbergstr. 28, D-01277 Dresden, Germany.
    Vuoristo, P.
    Tampere University of Technology, Department of Materials Science, Korkeakoulunkatu 6, FI-33720 Tampere, Finland.
    Tribology of HVOF- and HVAF-sprayed WC-10Co4Cr hardmetal coatings: A comparative assessment2015In: Surface and Coatings Technology, ISSN 0257-8972, Vol. 265, p. 125-144Article in journal (Refereed)
    Abstract [en]

    his paper provides a comprehensive assessment of the sliding and abrasive wear behaviour of WC–10Co4Cr hardmetal coatings, representative of the existing state-of-the-art. A commercial feedstock powder with two different particle size distributions was sprayed onto carbon steel substrates using two HVOF and two HVAF spray processes.Mild wear rates of < 10-7 mm3/(Nm) and friction coefficients of ≈ 0.5 were obtained for all samples in ball-on-disk sliding wear tests at room temperature against Al2O3 counterparts. WC–10Co4Cr coatings definitely outperform a reference electrolytic hard chromium coating under these test conditions. Their wear mechanisms include extrusion and removal of the binder matrix, with the formation of a wavy surface morphology, and brittle cracking. The balance of such phenomena is closely related to intra-lamellar features, and rather independent of those properties (e.g. indentation fracture toughness, elastic modulus) which mainly reflect large-scale inter-lamellar cohesion, as quantitatively confirmed by a principal component analysis. Intra-lamellar dissolution of WC into the matrix indeed increases the incidence of brittle cracking, resulting in slightly higher wear rates. At 400 °C, some of the hardmetal coatings fail because of the superposition between tensile residual stresses and thermal expansion mismatch stresses (due to the difference between the thermal expansion coefficients of the steel substrate and of the hardmetal coating). Those which do not fail, on account of lower residual stresses, exhibit higher wear rates than at room temperature, due to oxidation of the WC grains.The resistance of the coatings against abrasive wear, assessed by dry sand–rubber wheel testing, is related to inter-lamellar cohesion, as proven by a principal component analysis of the collected dataset. Therefore, coatings deposited from coarse feedstock powders suffer higher wear loss than those obtained from fine powders, as brittle inter-lamellar detachment is caused by their weaker interparticle cohesion, witnessed by their systematically lower fracture toughness as well.

  • 4.
    Bolelli, G.
    et al.
    University of Modena and Reggio Emilia, Dipartimento di Ingegneria 'Enzo Ferrari', Via P. Vivarelli 10/1, Modena, MO, Italy .
    Berger, L.-M.
    Fraunhofer-Institut für Werkstoff- und Strahltechnik (IWS), Winterbergstr. 28, Dresden, Germany.
    Börner, T.
    Fraunhofer-Institut für Werkstoff- und Strahltechnik (IWS), Winterbergstr. 28, Dresden, Germany.
    Koivuluoto, H.
    Tampere University of Technology, Department of Materials Science, Korkeakoulunkatu 6, Tampere, Finland .
    Matikainen, V.
    Tampere University of Technology, Department of Materials Science, Korkeakoulunkatu 6, Tampere, Finland .
    Lusvarghi, L.
    University of Modena and Reggio Emilia, Dipartimento di Ingegneria 'Enzo Ferrari', Via P. Vivarelli 10/1, Modena, MO, Italy .
    Lyphout, Christophe
    University West, Department of Engineering Science, Division of Production Engineering.
    Markocsan, Nicolaie
    University West, Department of Engineering Science, Division of Production Engineering.
    Nylén, Per
    University West, Department of Engineering Science, Research Enviroment Production Technology West.
    Sassatelli, P.
    University of Modena and Reggio Emilia, Dipartimento di Ingegneria 'Enzo Ferrari', Via P. Vivarelli 10/1, Modena, MO, Italy .
    Trache, R.
    Fraunhofer-Institut für Werkstoff- und Strahltechnik (IWS), Winterbergstr. 28, Dresden, Germany .
    Vuoristo, P.c
    Tampere University of Technology, Department of Materials Science, Korkeakoulunkatu 6, Tampere, Finlan.
    Sliding and abrasive wear behaviour of HVOF- and HVAF-sprayed Cr3C2-NiCr hardmetal coatings2016In: Wear, ISSN 0043-1648, E-ISSN 1873-2577, Vol. 358-359, p. 32-50Article in journal (Refereed)
    Abstract [en]

    This paper provides a comprehensive characterisation of HVOF- and HVAF-sprayed Cr3C2–25 wt.% NiCr hardmetal coatings. One commercial powder composition with two different particle size distributions was processed using five HVOF and HVAF thermal spray systems.All coatings contain less Cr3C2 than the feedstock powder, possibly due to the rebound of some Cr3C2-rich particles during high-velocity impact onto the substrate.Dry sand-rubber wheel abrasive wear testing causes both grooving and pull-out of splat fragments. Mass losses depend on inter- and intra-lamellar cohesion, being higher (≥70 mg after a wear distance of 5904 m) for the coatings deposited with the coarser feedstock powder or with one type of HVAF torch.Sliding wear at room temperature against alumina involves shallower abrasive grooving, small-scale delamination and carbide pull-outs, and it is controlled by intra-lamellar cohesion. The coatings obtained from the fine feedstock powder exhibit the lowest wear rates (≈5x10−6 mm3/(Nm)). At 400 °C, abrasive grooving dominates the sliding wear behaviour; wear rates increase by one order of magnitude but friction coefficients decrease from ≈0.7 to ≈0.5. The thermal expansion coefficient of the coatings (11.08x10−6 °C−1 in the 30–400 °C range) is sufficiently close to that of the steel substrate (14.23x10−6 °C−1) to avoid macro-cracking

  • 5.
    Cernuschi, F.
    et al.
    RSE – Ricerca per il Sistema Energetico, Via Rubattino, 54, 20134 Milano.
    Lorenzoni, L.
    RSE – Ricerca per il Sistema Energetico, Via Rubattino, 54, 20134 Milano.
    Capelli, S.
    RSE – Ricerca per il Sistema Energetico, Via Rubattino, 54, 20134 Milano.
    Guardamagna, C.
    RSE – Ricerca per il Sistema Energetico, Via Rubattino, 54, 20134 Milano.
    Karger, M.
    Forschungszentrum Jülich GmbH, Institut für Energieforschung IEF-1, 52425 Jülich.
    Vaßen, R.
    Forschungszentrum Jülich GmbH, Institut für Energieforschung IEF-1, 52425 Jülich.
    von Niessen, K.
    Sulzer Metco AG, Rigackerstr. 16, CH-5610, Wohlen.
    Markocsan, Nicolaie
    University West, Department of Engineering Science, Division of Production Engineering.
    Menuey, J.
    Snecma, 1 Rue Maryse Bastié, 86100 Châtellerault.
    Giolli, C.
    Turbocoating SpA, Via Mistrali 7, Rubbiano di Solignano,.
    Solid particle erosion of thermal spray and physical vapour deposition thermal barrier coatings2011In: Wear, Vol. 271, no 11-12, p. 2909-2918Article in journal (Refereed)
    Abstract [en]

    Thermal barrier coatings (TBC) are used to protect hot path components of gas turbines from hot combustion gases. For a number of decades, in the case of aero engines TBCs are usually deposited by electron beam physical vapour deposition (EB-PVD). EB-PVD coatings have a columnar microstructure that guarantees high strain compliance and better solid particle erosion than PS TBCs. The main drawback of EB-PVD coating is the deposition cost that is higher than that of air plasma sprayed (APS) TBC. The major scientific and technical objective of the UE project TOPPCOAT was the development of improved TBC systems using advanced bonding concepts in combination with additional protective functional coatings. The first specific objective was to use these developments to provide a significant improvement to state-of-the-art APS coatings and hence provide a cost-effective alternative to EB-PVD. In this perspective one standard porous APS, two segmented APS, one EB-PVD and one PS-PVD™ were tested at 700°C in a solid particle erosion jet tester, with EB-PVD and standard porous APS being the two reference systems.Tests were performed at impingement angles of 30° and 90°, representative for particle impingement on trailing and leading edges of gas turbine blades and vanes, respectively. Microquartz was chosen as the erodent being one of the main constituents of sand and fly volcanic ashes. After the end of the tests, the TBC microstructure was investigated using electron microscopy to characterise the failure mechanisms taking place in the TBC.It was found that PS-PVD™ and highly segmented TBCs showed erosion rates comparable or better than EB-PVD samples. © 2011 Elsevier B.V.

  • 6.
    Chen, Y.
    et al.
    University of Manchester, School of Materials, Manchester, United Kingdom.
    Zhao, X.
    Shanghai Jiao Tong University, Shanghai Key Laboratory of Advanced High-Temperature Materials and Precision Forming, Shanghai, China .
    Dang, Y.
    University of Manchester, School of Materials, Manchester, United Kingdom.
    Xiao, Ping
    University of Manchester, School of Materials, Manchester, United Kingdom.
    Curry, Nicholas
    University West, Department of Engineering Science, Division of Mechanical Engineering.
    Markocsan, Nicolaie
    University West, Department of Engineering Science, Division of Manufacturing Processes.
    Nylén, Per
    University West, Department of Engineering Science, Division of Production Engineering.
    Characterization and understanding of residual stresses in a NiCoCrAlY bond coat for thermal barrier coating application2015In: Acta Materialia, ISSN 1359-6454, E-ISSN 1873-2453, Vol. 94, p. 1-14Article in journal (Refereed)
    Abstract [en]

    The residual stresses in a NiCoCrAlY bond coat deposited on a Ni-base superalloy substrate after oxidation at 1150 °C were studied by X-ray diffraction using the sin2Ψ technique. The stresses were found to be tensile; they first increased and then decreased with oxidation time. High temperature stress measurement indicated that the stress developed and built up upon cooling, predominantly within the temperature range from 1150 °C to 600 °C. Microstructural examination suggested that, due to the limited penetration depth into the bond coat, the X-ray only probed the stress in a thin surface layer consisting of the single γ-phase formed through Al depletion during oxidation. Quantitative high temperature X-ray diffraction analysis revealed that, above 600 °C, the volume fraction of the β-phase in the bond coat increased with decreasing temperature. The mechanisms of stress generation in the bond coat were examined and are discussed based on the experiments designed to isolate the contribution of possible stress generation factors. It was found that the measured bond coat stresses were mainly induced by the volume change of the bond coat associated with the precipitation of the β-phase upon cooling.

  • 7.
    Clement, C.
    et al.
    National School of Engineers, University of Limoges, Limoges, 87280, France.
    Sadeghimeresht, Esmaeil
    University West, Department of Engineering Science, Division of Manufacturing Processes.
    Lyphout, Christophe
    University West, Department of Engineering Science, Division of Manufacturing Processes.
    Markocsan, Nicolaie
    University West, Department of Engineering Science, Division of Manufacturing Processes.
    Nylén, Per
    University West, Department of Engineering Science, Division of Production Engineering.
    Corrosion behavior of HVAF- and HVOF-sprayed high-chromium Fe-based coatings2015Conference paper (Refereed)
    Abstract [en]

    Fe-based coatings with three particular elemental compositions and two different powder particle size were prepared by high-velocity air fuel (HVAF) and high-velocity oxy fuel (HVOF) techniques. The corrosion behavior of which were comparatively studied in 3.5 wt.% NaCl solution. The results indicated that the coatings produced by HVAF process exhibited denser structure with lower porosity. Polarization and electrochemical impedance spectroscopy (EIS) tests indicated that the HVAF coatings provided better corrosion resistance than the HVOF coatings. The presence of defects was significant in HVOF coatings. The investigation illustrated that the corrosion paths initiated and grow through defects of the coating. Furthermore, adding Cr strongly improved the corrosion resistance of the coatings. The results confirmed that the cheap HVAF process could be a potential alternative to HVOF to fabricate Fe-based coatings for industrial applications.

  • 8.
    Curry, Nicholas
    et al.
    University West, Department of Engineering Science, Division of Mechanical Engineering.
    Janikowski, Wysomir
    University of Manchester.
    Pala, Zdenek
    Academy of Sciences of the Czech Republic, Institute of Plasma Physics.
    Vilémová, Monica
    Academy of Sciences of the Czech Republic, Institute of Plasma Physics.
    Markocsan, Nicolaie
    University West, Department of Engineering Science, Division of Production Engineering.
    Impact of Impurity Content on the Sintering Resistance and Phase Stability of Dysprosia- and Yttria-Stabilized Zirconia Thermal Barrier Coatings2014In: Journal of thermal spray technology (Print), ISSN 1059-9630, E-ISSN 1544-1016, Vol. 23, no 1-2, p. 160-169Article in journal (Refereed)
    Abstract [en]

    Dysprosia-stabilized zirconia (DySZ) is a promising candidate to replace yttria-stabilized zirconia (YSZ) as a thermal barrier coating due to its lower inherent thermal conductivity. It is also suggested in studies that DySZ may show greater stability to high temperature phase changes compared to YSZ, possibly allowing for coatings with extended lifetimes. Separately, the impurity content of YSZ powders has been proven to influence high-temperature sintering behavior. By lowering the impurity oxides within the spray powder, a coating more resistant to sintering can be produced. This study presents both high purity and standard purity dysprosia and YSZ coatings and their performance after a long heat treatment. Coatings were produced using powder with the same morphology and grain size; only the dopant and impurity content were varied. Samples have been heat treated for exposure times up to 400 h at a temperature of 1150 °C. Samples were measured for thermal conductivity to plot the evolution of coating thermal properties with respect to exposure time. Thermal conductivity has been compared to microstructure analysis and porosity measurement to track structural changes. Phase analysis utilizing x-ray diffraction was used to determine differences in phase degradation of the coatings after heat treatment. © 2013 ASM International.

  • 9.
    Curry, Nicholas
    et al.
    University West, Department of Engineering Science, Division of Mechanical Engineering.
    Janikowski, Wyszomir
    University of Mancheste.
    Markocsan, Nicolaie
    University West, Department of Engineering Science, Division of Production Engineering.
    Impact of impurity content on the sintering resistance of dysprosia and yttria stabilised zirconia thermal barrier coatings2013In: Proceedings of the International Thermal Spray Conference / [ed] Editor: Rogerio S. Lima, Arvind Agarwal, Margaret M. Hyland, Yuk-Chiu Lau, Georg Mauer, André McDonald, and Filofteia-Laura, ASM International, 2013, p. 557-563Conference paper (Refereed)
    Abstract [en]

    Dysprosia stabilised zirconia (DySZ) is a promising candidate to replace yttria stabilised zirconia (YSZ) as a thermal barrier coating due to its lower inherent thermal conductivity. It is also suggested in studies that DySZ may show greater stability to high temperature phase changes compared to YSZ, possibly allowing for coatings with extended lifetimes. Separately, the impurity content of YSZ powders has been proven to influence high temperature sintering behaviour. By lowering the impurity oxides within the spray powder, a coating more resistant to sintering can be produced. This study presents both high purity and standard purity dysprosia and yttria stabilised zirconia coatings and their performance after a long heat treatment. Coatings were produced using powder with the same morphology and grain size; only the dopant and impurity content were varied. Samples have been heat treated for exposure times up to 400 hours at a temperature of 1150°C. Samples were subsequently measured for thermal conductivity to plot the evolution of coating thermal properties with respect to exposure time. Thermal conductivity has been compared to microstructure analysis and porosity measurement to track structural changes due to sintering.

  • 10.
    Curry, Nicholas
    et al.
    University West, Department of Engineering Science, Division of Production Engineering.
    Markocsan, Nicolaie
    University West, Department of Engineering Science.
    Goddard, Caroline
    Manchester University.
    Influence of Sensor contact on the Thermal Conductivity Values of Thermal Barrier Coatings: Part 1 Experimental2010In: Proceedings of the 24th International Conference on Surface Modification Technologies: 7-9 sept, Dresden, 2010, p. 317-327Conference paper (Refereed)
  • 11.
    Curry, Nicholas
    et al.
    University West, Department of Engineering Science, Division of Manufacturing Processes.
    Markocsan, Nicolaie
    University West, Department of Engineering Science, Division of Manufacturing Processes.
    Li, Xin-Hai
    Siemens Turbomachinery.
    Tricoire, Aurelien
    Volvo Aero Corp.
    Dorfman, Mitch
    Sulzer Metco.
    Next Generation Thermal Barrier Coatings for the Gas Turbine Industry2010In: Journal of thermal spray technology (Print), ISSN 1059-9630, E-ISSN 1544-1016, ISSN 1059-9630, Vol. 20, no 1-2, p. 108-115Article in journal (Refereed)
    Abstract [en]

    The aim of this study is to develop the next generation of production ready air plasma sprayed thermalbarrier coating with a low conductivity and long lifetime. A number of coating architectures wereproduced using commercially available plasma spray guns. Modifications were made to powder chemistry,including high purity powders, dysprosia stabilized zirconia powders, and powders containingporosity formers. Agglomerated & sintered and homogenized oven spheroidized powder morphologieswere used to attain beneficial microstructures. Dual layer coatings were produced using the two powders.Laser flash technique was used to evaluate the thermal conductivity of the coating systems from roomtemperature to 1200 C. Tests were performed on as-sprayed samples and samples were heat treated for100 h at 1150 C. Thermal conductivity results were correlated to the coating microstructure using imageanalysis of porosity and cracks. The results show the influence of beneficial porosity on reducing thethermal conductivity of the produced coatings.

  • 12.
    Curry, Nicholas
    et al.
    University West, Department of Engineering Science, Division of Production Engineering.
    Markocsan, Nicolaie
    University West, Department of Engineering Science, Division of Production Engineering.
    Li, Xin-Hai
    Tricoire, Aurelien
    Dorfman, Mitchell
    Next Generation Thermal Barrier Coatings for the Gas Turbine Industry2010In: Proceedings of the Thermal Spray: Global Solutions for Future Application (ITSC 2010) Conference: Singapore, May 3-5, 2010, 2010, p. 716-722Conference paper (Refereed)
  • 13.
    Curry, Nicholas
    et al.
    University West, Department of Engineering Science, Division of Production Engineering.
    Markocsan, Nicolaie
    University West, Department of Engineering Science, Division of Production Engineering.
    Li, Xin-Hai
    Siemens Industrial Turbomachinery AB, Finspong, Sweden.
    Tricoire, Aurélien
    Volvo Aero, Trollhättan.
    Dorfman, Mitch
    Sulzer Metco, Westbury, United States.
    Next generation thermal barrier coatings for the gas turbine industry2011In: Journal of Thermal Spray Technology, Vol. 20, no 1-2, p. 108-115Article in journal (Refereed)
    Abstract [en]

    The aim of this study is to develop the next generation of production ready air plasma sprayed thermal barrier coating with a low conductivity and long lifetime. A number of coating architectures were produced using commercially available plasma spray guns. Modifications were made to powder chemistry, including high purity powders, dysprosia stabilized zirconia powders, and powders containing porosity formers. Agglomerated & sintered and homogenized oven spheroidized powder morphologies were used to attain beneficial microstructures. Dual layer coatings were produced using the two powders. Laser flash technique was used to evaluate the thermal conductivity of the coating systems from room temperature to 1200 °C. Tests were performed on as-sprayed samples and samples were heat treated for 100 h at 1150 °C. Thermal conductivity results were correlated to the coating microstructure using image analysis of porosity and cracks. The results show the influence of beneficial porosity on reducing the thermal conductivity of the produced coatings. © 2010 ASM International.

  • 14.
    Curry, Nicholas
    et al.
    University West, Department of Engineering Science, Division of Manufacturing Processes.
    Markocsan, Nicolaie
    University West, Department of Engineering Science, Division of Manufacturing Processes.
    Östergren, Lars
    Volvo Aero Corporation, Trollhättan.
    Li, Xin-Hai
    Siemens Industrial Turbomachinery, Finspång.
    Dorfman, Mitch
    Sulzer Metco, Westbury, USA.
    Evaluation of the Lifetime and Thermal Conductivity of Dysprosia-Stabilized Thermal Barrier Coating Systems2013In: Journal of thermal spray technology (Print), ISSN 1059-9630, E-ISSN 1544-1016, Vol. 22, no 6, p. 864-872Article in journal (Refereed)
    Abstract [en]

    The aim of this study was the further development of dysprosia stabilised zirconia coatings for gas turbine applications. The target for these coatings was a longer lifetime and higher insulating performance compared to today's industrial stan dard thermal barrier coating. Two morphologies of ceramic top coat were studied; one using a dual layer systems and the second using a polymer to generate porosity. Evaluations were carried out using laser flash technique to measure thermal properties. Lifetime testing was conducted using thermal shock testing and thermo-cyclic fatigue testing. Microstructure was assessed with SEM and Image analysis used to characterise porosity content. The results show that coatings with an engineered microstructure give performance twice that of the present reference coating.

  • 15.
    Curry, Nicholas
    et al.
    University West, Department of Engineering Science, Division of Mechanical Engineering.
    Tang, Zhaolin
    Northwest Mettech Corp., Vancouver, Canada.
    Markocsan, Nicolaie
    University West, Department of Engineering Science, Division of Production Engineering.
    Nylén, Per
    University West, Department of Engineering Science, Division of Production Engineering.
    Influence of Bond Coat Surface Roughness on the Structure of Axial Suspension Plasma Spray Thermal Barrier Coatings - Thermal and Lifetime Performance2015In: Surface & Coatings Technology, ISSN 0257-8972, E-ISSN 1879-3347, Vol. 268, no April, p. 15-23Article in journal (Refereed)
  • 16.
    Curry, Nicholas
    et al.
    University West, Department of Engineering Science, Division of Mechanical Engineering.
    VanEvery, Kent
    Progressive Surface, Grand Rapids, MI 49512, USA .
    Snyder, Todd
    Progressive Surface, Grand Rapids, MI 49512, USA.
    Markocsan, Nicolaie
    University West, Department of Engineering Science, Division of Manufacturing Processes.
    Thermal Conductivity Analysis and Lifetime Testing of Suspension Plasma-Sprayed Thermal Barrier Coatings2014In: Coatings, ISSN 2079-6412, Vol. 4, no 3, p. 630-650Article in journal (Refereed)
    Abstract [en]

    Suspension plasma spraying (SPS) has become an interesting method for the production of thermal barrier coatings for gas turbine components. The development of the SPS process has led to structures with segmented vertical cracks or column-like structures that can imitate strain-tolerant air plasma spraying (APS) or electron beam physical vapor deposition (EB-PVD) coatings. Additionally, SPS coatings can have lower thermal conductivity than EB-PVD coatings, while also being easier to produce. The combination of similar or improved properties with a potential for lower production costs makes SPS of great interest to the gas turbine industry. This study compares a number of SPS thermal barrier coatings (TBCs) with vertical cracks or column-like structures with the reference of segmented APS coatings. The primary focus has been on lifetime testing of these new coating systems. Samples were tested in thermo-cyclic fatigue at temperatures of 1100 °C for 1 h cycles. Additional testing was performed to assess thermal shock performance and erosion resistance. Thermal conductivity was also assessed for samples in their as-sprayed state, and the microstructures were investigated using SEM

  • 17.
    Fasth, Angelica
    et al.
    University West, Department of Engineering Science.
    Nylén, Per
    University West, Department of Engineering Science, Division of Production Engineering.
    Markocsan, Nicolaie
    University West, Department of Engineering Science.
    Musalek, Radek
    Characterization of thermo-mechanical properties for thermal sprayed NiCoCrAlY coatings2010In: Proceedings of the Thermal Spray: Global Solutions for Future Application (ITSC 2010) Conference: Singapore, May 3-5, 2010, 2010, p. 431-435Conference paper (Refereed)
  • 18.
    Ganvir, Ashish
    University West, Department of Engineering Science, Division of Subtractive and Additive Manufacturing.
    Joshi, Shrikant
    University West, Department of Engineering Science, Division of Subtractive and Additive Manufacturing.
    Influence of Isothermal Heat Treatment on Porosity and Crystallite Size in Axial Suspension Plasma Sprayed Thermal Barrier Coatings for Gas Turbine Applications2017In: Coatings, ISSN 2079-6412, Vol. 7, no 1, article id 4Article in journal (Refereed)
    Abstract [en]

    xial suspension plasma spraying (ASPS) is an advanced thermal spraying technique, which enables the creation of specific microstructures in thermal barrier coatings (TBCs) used for gas turbine applications. However, the widely varying dimensional scale of pores, ranging from a few nanometers to a few tenths of micrometers, makes it difficult to experimentally measure and analyze porosity in SPS coatings and correlate it with thermal conductivity or other functional characteristics of the TBCs. In this work, an image analysis technique carried out at two distinct magnifications, i.e., low (500×) and high (10,000×), was adopted to analyze the wide range of porosity. Isothermal heat treatment of five different coatings was performed at 1150 °C for 200 h under a controlled atmosphere. Significant microstructural changes, such as inter-columnar spacing widening or coalescence of pores (pore coarsening), closure or densification of pores (sintering) and crystallite size growth, were noticed in all the coatings. The noted changes in thermal conductivity of the coatings following isothermal heat treatment are attributable to sintering, crystallite size growth and pore coarsening

  • 19.
    Ganvir, Ashish
    et al.
    University West, Department of Engineering Science, Division of Manufacturing Processes.
    Curry, Nicholas
    University West, Department of Engineering Science, Division of Mechanical Engineering.
    Björklund, Stefan
    University West, Department of Engineering Science, Division of Manufacturing Processes.
    Markocsan, Nicolaie
    University West, Department of Engineering Science, Division of Manufacturing Processes.
    Nylén, Per
    University West, Department of Engineering Science, Division of Production Engineering.
    Characterization of Microstructure and Thermal Properties of YSZ Coatings Obtained by Axial Suspension Plasma Spraying (ASPS)2015In: Journal of thermal spray technology (Print), ISSN 1059-9630, E-ISSN 1544-1016, Vol. 24, no 7, p. 1195-1204Article in journal (Refereed)
    Abstract [en]

    The paper aims at demonstrating various microstructures which can be obtained using the suspension spraying technique and their respective significance in enhancing the thermal insulation property of a thermal barrier coating. Three different types of coating microstructures are discussed which were produced by the Axial Suspension Plasma Spraying. Detailed characterization of coatings was then performed. Optical and scanning electron microscopy were utilized for microstructure evaluations; x-ray diffraction for phase analysis; water impregnation, image analysis, and mercury intrusion porosimetry for porosity analysis, and laser flash analysis for thermal diffusivity measurements were used. The results showed that Axial Suspension Plasma Spraying can generate vertically cracked, porous, and feathery columnar-type microstructures. Pore size distribution was found in micron, submicron, and nanometer range. Higher overall porosity, the lower density of vertical cracks or inter-column spacing, and higher inter-pass porosity favored thermal insulation property of the coating. Significant increase in thermal diffusivity and conductivity was found at higher temperature, which is believed to be due to the pore rearrangement (sintering and pore coarsening). Thermal conductivity values for these coatings were also compared with electron beam physical vapor deposition (EBPVD) thermal barrier coatings from the literature and found to be much lower. © 2015 ASM International

  • 20.
    Ganvir, Ashish
    et al.
    University West, Department of Engineering Science, Division of Manufacturing Processes.
    Curry, Nicholas
    University West, Department of Engineering Science, Division of Manufacturing Processes.
    Markocsan, Nicolaie
    University West, Department of Engineering Science, Division of Manufacturing Processes.
    Govindarajan, Sivakumar
    International Advanced Research Centre for Powder Metallurgy and New Materials (ARCI), 500005 Hyderabad, India.
    Characterization of Thermal Barrier Coatings Produced by Various Thermal Spray Techniques Using Solid Powder, Suspension, and Solution Precursor Feedstock Material2016In: International Journal of Applied CeramicTechnology, ISSN 1744-7402, Vol. 13, no 2, p. 324-332Article in journal (Refereed)
    Abstract [en]

    Use of a liquid feedstock in thermal spraying (an alternative to the conventional solid powder feedstock) is receiving an increasing level of interest due to its capability to produce the advanced submicrometer/nanostructured coatings. Suspension plasma spraying (SPS) and solution precursor plasma spraying (SPPS) are those advanced thermal spraying techniques which help to feed this liquid feedstock. These techniques have shown to produce better performance thermal barrier coatings (TBCs) than conventional thermal spraying. In this work, a comparative study was performed between SPS- and SPPS-sprayed TBCs which then were also compared with the conventional atmospheric plasma-sprayed (APS) TBCs. Experimental characterization included SEM, porosity analysis using weight difference by water infiltration, thermal conductivity measurements using laser flash analysis, and lifetime assessment using thermo-cyclic fatigue test. It was concluded that SPS coatings can produce a microstructure with columnar type features (intermediary between the columnar and vertically cracked microstructure), whereas SPPS can produce vertically cracked microstructure. It was also shown that SPS coatings with particle size in suspension (D50) <3 μm were highly porous with lower thermal conductivity than SPPS and APS coatings. Furthermore, SPS coatings have also shown a relatively better thermal cyclic fatigue lifetime than SPPS.

  • 21.
    Ganvir, Ashish
    et al.
    University West, Department of Engineering Science, Division of Manufacturing Processes.
    Curry, Nicholas
    University West, Department of Engineering Science, Division of Mechanical Engineering.
    Markocsan, Nicolaie
    University West, Department of Engineering Science, Division of Production Engineering.
    Nylén, Per
    University West, Department of Engineering Science, Division of Production Engineering.
    Joshi, Shrikant
    University West, Department of Engineering Science, Research Enviroment Production Technology West.
    Vilemova, Monika
    IPP.
    Pala, Zdenek
    IPP.
    Influence of Microstructure on Thermal Properties of Axial Suspension Plasma-Sprayed YSZ Thermal Barrier Coatings2016In: Journal of thermal spray technology (Print), ISSN 1059-9630, E-ISSN 1544-1016, Vol. 25, no 1-2, p. 202-212Article in journal (Refereed)
    Abstract [en]

    Suspension plasma spraying is a relatively new thermal spaying technique to produce advanced thermal barrier coatings (TBCs) and enables production of coatings with a variety of structures—highly dense, highly porous, segmented, or columnar. This work investigates suspension plasma-sprayed TBCs produced using axial injection with different process parameters. The influence of coating microstructure on thermal properties was of specific interest. Tests carried out included microstructural analysis, phase analysis, determination of porosity, and pore size distribution, as well as thermal diffusivity/conductivity measurements. Results showed that axial suspension plasma spraying process makes it possible to produce various columnar-type coatings under different processing conditions. Significant influence of microstructural features on thermal properties of the coatings was noted. In particular, the process parameter-dependent microstructural attributes, such as porosity, column density, and crystallite size, were shown to govern the thermal diffusivity and thermal conductivity of the coating.

  • 22.
    Ganvir, Ashish
    et al.
    University West, Department of Engineering Science, Division of Manufacturing Processes.
    Curry, Nicholas
    University West, Department of Engineering Science, Division of Manufacturing Processes.
    Markocsan, Nicolaie
    University West, Department of Engineering Science, Division of Manufacturing Processes.
    Nylén, Per
    University West, Department of Engineering Science, Research Environment Production Technology West.
    Toma, Filofteia-Laura
    Fraunhofer Institute for Material and Beam Technology, Dresden, Germany.
    Comparative study of suspension plasma sprayed and suspension high velocity oxy-fuel sprayed YSZ thermal barrier coatings2015In: Surface and Coatings Technology, ISSN 0257-8972, Vol. 268, p. 70-76Article in journal (Refereed)
    Abstract [en]

    Suspension Thermal Spraying is a relatively new thermal spaying technique to produce advanced thermal barrier coatings. This technique enables the production of much different performance thermal barrier coatings than conventional thermal spraying which uses solid powder as a feedstock material. In this work a comparative study is performed on four different types of thermal barrier coatings sprayed with two different thermal spay processes, suspension high velocity oxy-fuel spraying (SHVOF) and suspension plasma spraying (SPS) using two different water-based suspensions. Tests carried out include microstructural analysis with SEM, porosity analysis using weight difference by water infiltration, thermal conductivity measurements using laser flash analysis and lifetime assessment using thermo-cyclic fatigue tests. The results showed that SPS coatings were much porous and hence showed lower thermal conductivity than SHVOF coatings produced with the same suspension. From the thermo-cycling tests it was observed that the SPS coatings showed a higher lifetime than the SHVOF ones.

  • 23.
    Ganvir, Ashish
    et al.
    University West, Department of Engineering Science, Research Enviroment Production Technology West.
    Curry, Nicholas
    University West, Department of Engineering Science, Division of Mechanical Engineering.
    Markocsan, Nicolaie
    University West, Department of Engineering Science, Division of Manufacturing Processes.
    Nylén, Per
    University West, Department of Engineering Science, Research Enviroment Production Technology West.
    Vilemova, Monika
    IPP Prague, Czech Republic.
    Pala, Zdenek
    IPP Prague, Czech Republic.
    Influence of Microstructure on Thermal Properties of Columnar Axial Suspension Plasma Sprayed Thermal Barrier Coatings2015In: Thermal Spray 2015: Proceedings from the International Thermal Spray Conference (May 11–14, 2015, Long Beach, California, USA) / [ed] A. McDonald, A. Agarwal, G. Bolelli, A. Concustell, Y.-C. Lau, F.-L. Toma, E. Turunen, C. Widener, 2015, p. 498-505Conference paper (Refereed)
    Abstract [en]

    Suspension Plasma Spraying is a relatively new thermal spraying technique to produce advanced thermal barrier coatings. This technique enables the production of a variety of structures from highly dense, highly porous, segmented or columnar coatings. In this work a comparative study is performed on six different suspension plasma sprayed thermal barrier coatings which were produced using axial injection and different process parameters. The influence of coating morphology and porosity on thermal properties was of specific interest. Tests carried out include microstructural analysis with SEM, phase analysis using XRD, porosity calculation using Archimedes experimental setup, pore distribution analysis using mercury infiltration technique and thermal diffusivity/conductivity measurements using laser flash analysis. The results showed that columnar and cauliflower type coatings were produced by axial suspension plasma spraying process. Better performance coatings were produced with relatively higher overall energy input given during spraying. Coatings with higher energy input, lower thickness and wider range of submicron and nanometer sized pores distribution showed lower thermal diffusivity and hence lower thermal conductivity. Also, in-situ heat treatment did not show dramatic increase in thermal properties.

  • 24.
    Ganvir, Ashish
    et al.
    University West, Department of Engineering Science, Division of Subtractive and Additive Manufacturing.
    Markocsan, Nicolaie
    University West, Department of Engineering Science, Division of Subtractive and Additive Manufacturing.
    Porosity analysis of axial suspension plasma sprayed thermal barrier coatings for gas turbine applications2016Conference paper (Other academic)
  • 25.
    Ganvir, Ashish
    et al.
    University West, Department of Engineering Science, Division of Subtractive and Additive Manufacturing.
    Markocsan, Nicolaie
    University West, Department of Engineering Science, Division of Subtractive and Additive Manufacturing.
    Gupta, Mohit Kumar
    University West, Department of Engineering Science, Division of Subtractive and Additive Manufacturing.
    Calinas, R.
    Vitorino, N.
    Lukac, F.
    Ekberg, J.
    Chalmers University of Technology, Sweden.
    Influence of suspension characteristics on microstructure of axial suspension plasma-sprayed coatings2017Conference paper (Other academic)
  • 26.
    Ganvir, Ashish
    et al.
    University West, Department of Engineering Science, Division of Subtractive and Additive Manufacturing.
    Markocsan, Nicolaie
    University West, Department of Engineering Science, Division of Subtractive and Additive Manufacturing.
    Lukac, F.
    Pala, Z.
    Influence of microstructure on thermo-cyclic fatigue and thermal shock resistance of axial suspension plasma sprayed therm2016Conference paper (Other academic)
  • 27.
    Ganvir, Ashish
    et al.
    University West, Department of Engineering Science, Division of Subtractive and Additive Manufacturing.
    Vaidhyanathan, Venkateswaran
    University West, Department of Engineering Science.
    Markocsan, Nicolaie
    University West, Department of Engineering Science, Division of Subtractive and Additive Manufacturing.
    Gupta, Mohit Kumar
    University West, Department of Engineering Science, Division of Subtractive and Additive Manufacturing.
    Pala, Zdenek
    Institute of Plasma Physics CAS, Za Slovankou 3, 182 00 Prague, Czech Republic.
    Lukac, Frantisek
    Institute of Plasma Physics CAS, Za Slovankou 3, 182 00 Prague, Czech Republic.
    Failure analysis of thermally cycled columnar thermal barrier coatings produced by high-velocity-air fuel and axial-suspension-plasma spraying: A design perspective2018In: Ceramics International, ISSN 0272-8842, E-ISSN 1873-3956, Vol. 44, no 3, p. 3161-3172Article in journal (Refereed)
    Abstract [en]

    Axial-suspension-plasma spraying (ASPS) is a fairly recent thermal spray technology which enables production of ceramic top coats in TBCs, incorporating simultaneously the properties of both the conventional-plasma sprayed (highly insulating porous structures) and electron-beam-physical-vapor-deposited (strain-tolerant columnar structures) top coats. TBCs are required to insulate the hot components in a gas turbine engine against high temperature and harsh operating conditions. Periodic heating and cooling of turbine engines during operation can create severe thermal cyclic fatigue conditions which can degrade the performance of these coatings eventually leading to the failure. An in-depth experimental investigation was performed to understand the failure behavior of columnar TBCs subjected to thermal cyclic fatigue (TCF) test at 1100 C. The study revealed that the TCF performance was influenced to an extent, by the top coat microstructure, but was primarily affected by the severity of thermally grown oxide (TGO) growth at the bond coat-top coat interface. Mixed failure modes comprising crack propagation through the bond coat-TGO interface, through TGO and within the top coat were identified. Based on the analysis of the experimental results and thorough discussion a novel design of microstructure for the high TCF performance columnar TBC is proposed. © 2017 Elsevier Ltd and Techna Group S.r.l.

  • 28.
    Guerin, Elie
    et al.
    National School of Engineers, University of Limoges, Limoges, France.
    Sadeghimeresht, Esmaeil
    University West, Department of Engineering Science, Division of Subtractive and Additive Manufacturing.
    Markocsan, Nicolaie
    University West, Department of Engineering Science, Division of Subtractive and Additive Manufacturing.
    Joshi, Shrikant V.
    University West, Department of Engineering Science, Research Enviroment Production Technology West.
    Role of Chemistry on Corrosion Behavior of Various Ni-based HVAF-Sprayed Coatings in Simulated Boiler Environments2017Conference paper (Other academic)
  • 29.
    Gupta, Mohit Kumar
    et al.
    University West, Department of Engineering Science, Division of Manufacturing Processes.
    Curry, Nicholas
    University West, Department of Engineering Science, Division of Manufacturing Processes.
    Markocsan, Nicolaie
    University West, Department of Engineering Science, Division of Production Engineering.
    Nylén, Per
    University West, Department of Engineering Science, Division of Production Engineering.
    Vaßen, Robert
    University West, Department of Engineering Science, Research Enviroment Production Technology West.
    Design of Next Generation Thermal Barrier Coatings- Experiments and Modelling2013In: Surface and Coatings Technology, ISSN 0257-8972, Vol. 220, p. 20-26Article in journal (Refereed)
    Abstract [en]

    Thermal barrier coating (TBC) systems have been used in the gas turbine industry since the 1980's. The future needs of both the air and land based turbine industry involve higher operating temperatures with longer lifetime on the component so as to increase power and efficiency of gas turbines. The aim of this study was to meet these future needs by further development of zirconia coatings. The intention was to design a coating system which could be implemented in industry within the next three years. Different morphologies of ceramic topcoat were evaluated; using dual layer systems and polymers to generate porosity. Dysprosia stabilised zirconia was also included in this study as a topcoat material along with the state-of-the-art yttria stabilised zirconia (YSZ). High purity powders were selected in this work. Microstructure was assessed with scanning electron microscope and an in-house developed image analysis routine was used to characterise porosity content. Evaluations were carried out using the laser flash technique to measure thermal conductivity. Lifetime was assessed using thermo-cyclic fatigue testing. Finite element analysis was utilised to evaluate thermal-mechanical material behaviour and to design the morphology of the coating with the help of an artificial coating morphology generator through establishment of relationships between microstructure, thermal conductivity and stiffness. It was shown that the combined empirical and numerical approach is an effective tool for developing high performance coatings. The results show that large globular pores and connected cracks inherited within the coating microstructure result in a coating with best performance. A low thermal conductivity coating with twice the lifetime compared to the industrial standard today was fabricated in this work.

  • 30.
    Gupta, Mohit Kumar
    et al.
    University West, Department of Engineering Science, Division of Subtractive and Additive Manufacturing.
    Kuhn, J.
    Kesler, O.
    Markocsan, Nicolaie
    University West, Department of Engineering Science, Division of Subtractive and Additive Manufacturing.
    Influence of Process Parameters on Microstructure and Permeability of Axial Suspension Plasma Sprayed Electrolytes in SOFCs2016Conference paper (Other academic)
  • 31.
    Gupta, Mohit Kumar
    et al.
    University West, Department of Engineering Science, Division of Subtractive and Additive Manufacturing.
    Markocsan, Nicolaie
    University West, Department of Engineering Science, Division of Subtractive and Additive Manufacturing.
    Li, X. -H
    Siemens Industrial Turbomachinery AB, Finspång, Sweden.
    Östergren, Lars
    GKN Aerospace, Trollhättan, Sweden.
    Influence of Bondcoat Spray Process on Lifetime of Suspension Plasma-Sprayed Thermal Barrier Coatings2018In: Journal of thermal spray technology (Print), ISSN 1059-9630, E-ISSN 1544-1016, Vol. 27, no 1-2, p. 84-97Article in journal (Refereed)
    Abstract [en]

    Development of thermal barrier coatings (TBCs) manufactured by suspension plasma spraying (SPS) is of high commercial interest as SPS has been shown capable of producing highly porous columnar microstructures similar to the conventionally used electron beam–physical vapor deposition. However, lifetime of SPS coatings needs to be improved further to be used in commercial applications. The bondcoat microstructure as well as topcoat–bondcoat interface topography affects the TBC lifetime significantly. The objective of this work was to investigate the influence of different bondcoat deposition processes for SPS topcoats. In this work, a NiCoCrAlY bondcoat deposited by high velocity air fuel (HVAF) was compared to commercial vacuum plasma-sprayed NiCoCrAlY and PtAl diffusion bondcoats. All bondcoat variations were prepared with and without grit blasting the bondcoat surface. SPS was used to deposit the topcoats on all samples using the same spray parameters. Lifetime of these samples was examined by thermal cyclic fatigue testing. Isothermal heat treatment was performed to study bondcoat oxidation over time. The effect of bondcoat deposition process and interface topography on lifetime in each case has been discussed. The results show that HVAF could be a suitable process for bondcoat deposition in SPS TBCs.

  • 32.
    Gupta, Mohit Kumar
    et al.
    University West, Department of Engineering Science, Division of Subtractive and Additive Manufacturing.
    Markocsan, Nicolaie
    University West, Department of Engineering Science, Division of Subtractive and Additive Manufacturing.
    Li, X.
    Kjellman, B.
    Effect of bondcoat and substrate chemistry on oxide growth and lifetime in suspension plasma sprayed thermal barrier coatings2017Conference paper (Other academic)
  • 33.
    Gupta, Mohit Kumar
    et al.
    University West, Department of Engineering Science, Division of Subtractive and Additive Manufacturing.
    Markocsan, Nicolaie
    University West, Department of Engineering Science, Division of Subtractive and Additive Manufacturing.
    Li, X-H
    Influence of topcoat-bondcoat interface on lifetime in suspension sprayed therma barrier coatings2016Conference paper (Other academic)
  • 34.
    Gupta, Mohit Kumar
    et al.
    University West, Department of Engineering Science, Division of Subtractive and Additive Manufacturing.
    Markocsan, Nicolaie
    University West, Department of Engineering Science, Division of Subtractive and Additive Manufacturing.
    Li, Xin-Hai
    Siemens Industrial Turbomachinery AB, Finspong, Sweden.
    Peng, Ru Lin
    Linköping University, Linköping, Sweden.
    Improving the lifetime of suspension plasma sprayed thermal barrier coatings2017In: Surface & Coatings Technology, ISSN 0257-8972, E-ISSN 1879-3347, Vol. 332, p. 550-559Article in journal (Refereed)
    Abstract [en]

    Development of thermal barrier coating systems (TBCs) for gas turbine applications allowing higher combustion temperatures is of high interest since it results in higher fuel efficiency and lower emissions. TBCs produced by suspension plasma spraying (SPS) have been shown to exhibit significantly lower thermal conductivity as compared to conventional systems due to their very fine porosity microstructure. However they have not been commercialised yet due to low reliability and life expectancy of the coatings. In addition to the initial topcoat microstructure and its sintering resistance, lifetime of a TBC system is highly dependent on bondcoat chemistry as it influences the growth rate of thermally grown oxide (TGO) layer. To enhance the lifetime of SPS TBCs, fundamental understanding of relationships between topcoat microstructure and its evolution with time, bondcoat chemistry, TGO growth rate, and lifetime is essential. The objective of this work was to study the effect of topcoat microstructure evolution and TGO growth rate on lifetime in SPS TBC systems. Experimental MCrAlY bondcoat powders with different aluminium activities were investigated and compared to a commercial bondcoat powder. High velocity air fuel spraying was used for bondcoat deposition while axial-SPS was used for yttria stabilized zirconia topcoat deposition. Lifetime was examined by thermal cyclic fatigue testing. Isothermal heat treatment was performed to study TGO evolution with time. The changes in microstructure of SPS coatings due to sintering under long term exposure at high temperatures were investigated. Different failure modes in SPS TBCs were also examined. The bondcoat with higher aluminium activity resulted in a significantly higher thermal cyclic lifetime of the corresponding TBC as it could have promoted protective alumina layer growth for a longer period of time. The results indicate that the significant changes in topcoat microstructure due to sintering as observed in this work could have a detrimental effect on TBC lifetime. © 2017 Elsevier B.V.

  • 35.
    Gupta, Mohit Kumar
    et al.
    University West, Department of Engineering Science, Division of Subtractive and Additive Manufacturing.
    Markocsan, Nicolaie
    University West, Department of Engineering Science, Division of Subtractive and Additive Manufacturing.
    Li, Xin-Hai
    Siemens Industrial Turbomachinery, Finspång, Sweden.
    Östergren, Lars
    GKN Aerospace, Trollhättan, Sweden.
    Development of bondcoat layer for long lifetime suspension plasma sprayed thermal barrier coatings2017In: ISTC 2017: International Thermal Spray Conference & Exposition: abstracts (including proceedings on USB stick), Düsseldorf: DVS Media , 2017, p. 70-Conference paper (Refereed)
    Abstract [en]

    Development of thermal barrier coatings (TBCs) manufactured by suspension plasma spraying (SPS) is of high commercial interest as SPS has been shown capable to produce columnar microstructures similar to the conventionally used electron beam – physical vapour deposition (EB-PVD) process. Moreover, SPS is a significantly cheaper process and can also produce more porous coatings than EB-PVD. However, lifetime of SPS coatings needs to be improved further for them to be applicable in commercial applications.The bondcoat microstructure as well as topcoat-bondcoat interface topography affect the TBC lifetime significantly. The objective of this work was to investigate the feasibility of different bondcoat deposition process for SPS TBCs. In this work, a NiCoCrAlY bondcoat deposited by high velocity air fuel (HVAF) was compared to commercial NiCoCrAlY and PtAl bondcoats. All bondcoat variations were prepared with and without grit blasting the bondcoat surface. SPS was used to deposit the topcoats on all samples using the same spray parameters. Lifetime of these samples was examined by thermal cyclic fatigue and thermal shock testing. The effect of bondcoat deposition process and interface topography on lifetime in each case has been discussed. The results show that HVAF could be a suitable process for bondcoat deposition in SPS TBCs.

  • 36.
    Gupta, Mohit Kumar
    et al.
    University West, Department of Engineering Science, Division of Subtractive and Additive Manufacturing.
    Markocsan, Nicolaie
    University West, Department of Engineering Science, Division of Subtractive and Additive Manufacturing.
    Rocchio-Heller, R.
    Oerlikon Metco, Westbury, USA.
    Liu, J.
    Oerlikon Metco, Westbury, USA.
    Li, X. -H
    Siemens Industrial Turbomachinery AB, Finspång, Sweden.
    Östergren, L.
    GKN Aerospace, Trollhättan, Sweden.
    Failure Analysis of Multilayered Suspension Plasma-Sprayed Thermal Barrier Coatings for Gas Turbine Applications2018In: Journal of thermal spray technology (Print), ISSN 1059-9630, E-ISSN 1544-1016Article in journal (Refereed)
    Abstract [en]

    Improvement in the performance of thermal barrier coatings (TBCs) is one of the key objectives for further development of gas turbine applications. The material most commonly used as TBC topcoat is yttria-stabilized zirconia (YSZ). However, the usage of YSZ is limited by the operating temperature range which in turn restricts the engine efficiency. Materials such as pyrochlores, perovskites, rare earth garnets are suitable candidates which could replace YSZ as they exhibit lower thermal conductivity and higher phase stability at elevated temperatures. The objective of this work was to investigate different multilayered TBCs consisting of advanced topcoat materials fabricated by suspension plasma spraying (SPS). The investigated topcoat materials were YSZ, dysprosia-stabilized zirconia, gadolinium zirconate, and ceria–yttria-stabilized zirconia. All topcoats were deposited by TriplexPro-210TM plasma spray gun and radial injection of suspension. Lifetime of these samples was examined by thermal cyclic fatigue and thermal shock testing. Microstructure analysis of as-sprayed and failed specimens was performed with scanning electron microscope. The failure mechanisms in each case have been discussed in this article. The results show that SPS could be a promising route to produce multilayered TBCs for high-temperature applications.

  • 37.
    Gupta, Mohit Kumar
    et al.
    University West, Department of Engineering Science, Division of Subtractive and Additive Manufacturing.
    Markocsan, Nicolaie
    University West, Department of Engineering Science, Division of Subtractive and Additive Manufacturing.
    Rocchio-Heller, Riston
    Oerlikon Metco, Westbury, USA.
    Liu, Jing
    Oerlikon Metco, Westbury, USA.
    Li, Xin-Hai
    Siemens Industrial Turbomachinery, Fingspång, Sweden.
    Östergren, Lars
    GKN Aerospace, Trollhättan, Sweden.
    Multilayered suspension plasma sprayed thermal barrier coatings for high temperature gas turbine applications2017In: ISTC 2017: International Thermal Spray Conference & Exposition : abstracts (including proceedings on USB stick), Düsseldorf: DVS Media , 2017, p. 1-6Conference paper (Refereed)
    Abstract [en]

    Improvement in the performance of thermal barrier coating systems (TBCs) is one of the key objectives for further development of gas turbine applications. The material most commonly used as TBC topcoat is yttria stabilised zirconia (YSZ). However, the usage of YSZ is limited by the operating temperature range which in turn restricts the engine efficiency. Materials such as pyrochlores, perovskites, rare earth garnets, etc. are suitable candidates which could replace YSZ as they exhibit lower thermal conductivity and higher phase stability at elevated temperatures.The objective of this work was to investigate different multi-layered TBCs consisting of advanced topcoat materials fabricated by Suspension Plasma Spraying (SPS). The investigated topcoat materials were YSZ, dysprosia stabilised zirconia, gadolinium zirconiate, cerium doped YSZ and yttria fully stabilised zirconia. All topcoats were deposited with TriplexPro-210 plasma spray gun and radial injection of suspension. Lifetime of these samples was examined by thermal cyclic fatigue and thermal shock testing. Microstructure analysis of as-sprayed and failed specimens was performed with scanning electron microscope. The failure mechanisms in each case have been discussed in this article. The results show that SPS could be a promising route to produce multilayered TBCs for high temperature applications.

  • 38.
    Gupta, Mohit Kumar
    et al.
    University West, Department of Engineering Science, Division of Manufacturing Processes.
    Weber, A.
    Karlsruhe Institute of Technology, Karlsruhe, Germany .
    Markocsan, Nicolaie
    University West, Department of Engineering Science, Division of Production Engineering.
    Gindrat, M.
    Oerlikon Metco, Wohlen, Switzerland.
    Electrochemical performance of plasma sprayed metal supported planar solid oxide fuel cells2015In: ECS Transactions, ISSN 1938-5862, E-ISSN 1938-6737, Vol. 68, no 1, p. 1791-1802Article in journal (Refereed)
    Abstract [en]

    High production cost is one of the major barriers to widespread commercialization of solid oxide fuel cells (SOFCs). Thermal spray techniques are a low cost alternative for the production of SOFCs. The objective of this work was to evaluate the electrochemical performance of half-cells produced by plasma spraying. The anode was deposited on a porous metallic support by atmospheric plasma spraying (APS) whereas the electrolyte was deposited by plasma spray-thin film (PS-TF) technique which can produce thin and dense coatings at high deposition rates. The cathode was deposited by screen-printing. The electrochemical tests were performed at 650-800°C. Current-voltage characteristics and impedance spectra were measured and analyzed. The impact of electrolyte composition and layer thickness on the gas tightness of the electrolyte and the area specific resistance of the cell is discussed. The results show that the applied thermal spraying techniques are a potential alternative for producing SOFCs. © The Electrochemical Society.

  • 39.
    Gupta, Mohit Kumar
    et al.
    University West, Department of Engineering Science, Division of Subtractive and Additive Manufacturing.
    Weber, André
    Karlsruhe Institute of Technology, Germany.
    Markocsan, Nicolaie
    University West, Department of Engineering Science, Division of Subtractive and Additive Manufacturing.
    Gindrat, Malko
    Oerlikon Metco, Switzerland.
    Electrochemical Performance of Plasma Sprayed Metal Supported Planar Solid Oxide Fuel Cells2016In: Journal of the Electrochemical Society, ISSN 0013-4651, E-ISSN 1945-7111, Vol. 163, no 9, p. F1059-F1065Article in journal (Refereed)
    Abstract [en]

    High production cost is one of the major barriers to widespread commercialization of solid oxide fuel cells (SOFCs). Thermal spraytechniques are a low cost alternative for the production of SOFCs. The objective of this work was to evaluate the electrochemicalperformance of cells produced by plasma spraying. The anode was deposited on a porous metallic support by atmospheric plasmaspraying (APS) whereas the electrolyte was deposited by plasma spray-thin film (PS-TF) technique, which can produce thin anddense coatings at high deposition rates. The cathode was deposited by screen-printing and in-operando sintering. The electrochemicaltests were performed at 650–800◦C. Current-voltage characteristics and impedance spectra were measured and analyzed. The impactof electrolyte composition and layer thickness on the gas tightness of the electrolyte and the area specific resistance of the cell isdiscussed. The results show that the applied thermal spraying techniques are a potential alternative for producing SOFCs.

  • 40.
    Gupta, Mohit Kumar
    et al.
    University West, Department of Engineering Science, Division of Subtractive and Additive Manufacturing.
    Weber, André
    Karlsruhe Institute of Technology, Germany.
    Markocsan, Nicolaie
    University West, Department of Engineering Science, Division of Subtractive and Additive Manufacturing.
    Helden, Nadine
    Oerlikon Metco, Germany.
    Development of plasma sprayed Ni/YSZ anodes for metal supported solidoxide fuel cells2017In: Surface & Coatings Technology, ISSN 0257-8972, E-ISSN 1879-3347, Vol. 318, p. 178-189Article in journal (Refereed)
    Abstract [en]

    Solid oxide fuel cells (SOFCs) offer a promising technique for producing electricity by clean energy conversionthrough an electrochemical reaction of fuel and air. Plasma spraying could be a potential manufacturing routefor commercial SOFCs, as it provides a distinct advantage especially in case of metal supported cells (MSCs) byallowing rapid processing at relatively low processing temperatures preventing thus the degradation of themetallicsubstrate. The objective of this work was to develop nickel/yttria stabilised zirconia (Ni/YSZ) anodes withhigh porosity and homogeneous phase distribution by atmospheric plasma spraying forMSCs. Various feedstockmaterial approaches were explored in this study, both with single injection aswell as separate injection of differentfeedstock materials , and with and without the use of pore formers to create additional porosity. The advantagesand issues with each material route were investigated and discussed. It was shown that agglomerated Ni/YSZ/polyester feedstock material resulted in the best distribution of Ni and YSZ in the anodemicrostructurewithhomogeneous porosity. Subsequently, the Ni/YSZ/polyester material route with different amounts and size distributionsof polyester was chosen to develop anode symmetrical cells using a commercial zirconia sheet as supportfor electrochemical testing. The Ni/YSZ/polyester anode powder with 10 wt.% standard size polyesterexhibited the best electrochemical performance. The results show that plasma spraying of the agglomeratedNi/YSZ/polyester could be a promising route to achieve high performance and rapid production anodes withoutusing the carcinogenic nickel oxide.

  • 41.
    Jafari, R.
    et al.
    Department of Material Science and Engineering, Tarbiat Modares University, Tehran, Iran.
    Sadeghimeresht, Esmaeil
    University West, Department of Engineering Science, Division of Subtractive and Additive Manufacturing.
    Shahrabi Farahani, T.
    Department of Material Science and Engineering, Tarbiat Modares University, Tehran, Iran .
    Markocsan, Nicolaie
    University West, Department of Engineering Science, Division of Subtractive and Additive Manufacturing.
    Joshi, Shrikant V.
    University West, Department of Engineering Science, Division of Subtractive and Additive Manufacturing.
    KCl-induced corrosion behavior of HVAF-sprayed Ni-based coatings in ambient air2017Conference paper (Other academic)
  • 42.
    Jafari, Reza
    et al.
    Tarbiat Modares University, Department of Material Science and Engineering, Tehran, Iran.
    Sadeghimeresht, Esmaeil
    University West, Department of Engineering Science, Division of Subtractive and Additive Manufacturing.
    Shahrabi Farahani, Taghi
    Tarbiat Modares University, Department of Material Science and Engineering, Tehran, Iran.
    Huhtakangas, Matti
    M. H. Engineering AB, Karlskoga, Sweden .
    Markocsan, Nicolaie
    University West, Department of Engineering Science, Division of Subtractive and Additive Manufacturing.
    Joshi, Shrikant V.
    University West, Department of Engineering Science, Division of Subtractive and Additive Manufacturing.
    KCl-Induced High Temperature Corrosion Behavior of HVAF-Sprayed Ni-Based Coatings in Ambient Air2018In: Journal of thermal spray technology (Print), ISSN 1059-9630, E-ISSN 1544-1016, Vol. 27, no 1-2, p. 1-13Article in journal (Refereed)
    Abstract [en]

    KCl-induced high temperature corrosion behavior of four HVAF-sprayed Ni-based coatings (Ni21Cr, Ni5Al, Ni21Cr7Al1Y, and Ni21Cr9Mo) under KCl deposit has been investigated in ambient air at 600°C up to 168h. The coatings were deposited onto 16Mo3 steel - a widely used boiler tube material.Uncoated substrate, 304L and Sanicro25 were used as reference materials in the test environment.SEM/EDS and XRD techniques were utilized to characterize the as-sprayed and exposed samples.The results showed that the small addition of KCl significantly accelerated degradation to the coatings. All coatings provided better corrosion resistance compared to the reference materials. The alumina-forming Ni5Al coating under KCl deposit was capable of forming a more protective oxide scale compared to the chromia-forming coatings as penetration of Cl through diffusion paths was hindered. Both active corrosion and chromate formation mechanisms were found to be responsible for Page 1 of 23ASM the corrosion damages. The corrosion resistance of the coatings based on the microstructure analysis and kinetics had the following ranking (from the best to worst): Ni5Al >Ni21Cr> Ni21Cr7Al1Y>Ni21Cr9Mo.

  • 43.
    Jonnalagadda, K. P.
    et al.
    Linkoping University, Department of Manangement and Engineering,Linkoping, Sweden.
    Peng, R. L.
    Linkoping University, Department of Manangement and Engineering,Linkoping, Sweden.
    Mahade, Satyapal
    University West, Department of Engineering Science, Division of Subtractive and Additive Manufacturing.
    Markocsan, Nicolaie
    University West, Department of Engineering Science, Division of Subtractive and Additive Manufacturing.
    Nylén, Per
    University West, Department of Engineering Science, Division of Subtractive and Additive Manufacturing.
    Björklund, Stefan
    University West, Department of Engineering Science, Division of Subtractive and Additive Manufacturing.
    Curry, Nicholas
    Treibacher Industrie AG, Austria.
    Li, X. -H
    Siemens Industrial Turbomachinery AB, Finspang, Sweden.
    Hot corrosion behavior of multi-layer suspension plasma sprayed Gd2Zr2O7/YSZ thermal barrier coatings2017In: InterCeram: International Ceramic Review, ISSN 0020-5214, Vol. 66, no 5, p. 180-184Article in journal (Refereed)
    Abstract [en]

    This study investigates the corrosion resistance of double layer Gd2Zr2O7/YSZ, triple layer dense Gd2Zr2O7 / Gd2Zr2O7/YSZ and a reference single layer YSZ coating with a similar overall top coat thickness of 300-320 Όm. All the coatings were manufactured by suspension plasma spraying (SPS), resulting in a columnar structure. Corrosion tests were conducted at 900°C for 8 hours using vanadium pentoxide and sodium sulphate as corrosive salts at a concentration of 4 mg/cm2. SEM investigations after the corrosion tests show that Gd2Zr2O7 coatings exhibited lower corrosion resistance than the reference material, YSZ. Reaction between the corrosive salts and Gd2Zr2O7 results in the formation of gadolinium vanadate ( GdVO4) along the top surface and between the columns. While the stresses due to phase transformation of zirconia can be relieved to some extent by realigning of the columns in the top coat, it is believed that GdVO4 formation between the columns, along with low fracture toughness of Gd2Zr2O7 had resulted in lower corrosion resistance. Furthermore, the presence of a relatively dense layer of Gd2Zr2O7 on the top, as a preventive layer for salt infiltration, did not improve the corrosion resistance.

  • 44. Jonnalagadda, K.P.
    et al.
    Mahade, Satyapal
    University West, Department of Engineering Science, Division of Subtractive and Additive Manufacturing.
    Nicholas, Curry
    University West, Department of Engineering Science, Research Enviroment Production Technology West.
    Li, X-H.
    Markocsan, Nicolaie
    University West, Department of Engineering Science, Division of Subtractive and Additive Manufacturing.
    Nylen, Per
    University West, Department of Engineering Science, Division of Subtractive and Additive Manufacturing.
    Björklund, Stefan
    University West, Department of Engineering Science, Division of Subtractive and Additive Manufacturing.
    Peng, R.L.
    Hot corrosion behavior of multi-layer suspension plasma sprayed Gd2Zr2O7 /YSZ thermal barrier coatings2016In: Thermal Spray 2016: Proceedings from the International Thermal Spray Conference in Shanghai, P.R China, May 10-12, 2016, DVS – German Welding Society , 2016, Vol. 324, p. 261-266Conference paper (Refereed)
  • 45.
    Jonnalagadda, Krishna Praveen
    et al.
    Linköping University, Department of Management and Engineering, Linköping, Sweden.
    Mahade, Satyapal
    University West, Department of Engineering Science, Division of Subtractive and Additive Manufacturing.
    Nicholas, Curry
    Treibacher Ind AG, Althofen, Austria.
    Li, Xin-Hai
    Siemens Industrial Turbomachinery AB, Finspång, Sweden.
    Markocsan, Nicolaie
    University West, Department of Engineering Science, Division of Subtractive and Additive Manufacturing.
    Nylen, Per
    University West, Department of Engineering Science, Division of Subtractive and Additive Manufacturing.
    Björklund, Stefan
    University West, Department of Engineering Science, Division of Subtractive and Additive Manufacturing.
    Peng, Ru Lin
    Linköping University, Department of Management and Engineering, Linköping, Sweden.
    Hot Corrosion Mechanism in Multi-Layer Suspension Plasma Sprayed Gd2Zr2O7 /YSZ Thermal Barrier Coatings in the Presence of V2O5 + Na2SO42017In: Journal of thermal spray technology (Print), ISSN 1059-9630, E-ISSN 1544-1016, Vol. 26, no 1-2, p. 140-149Article in journal (Refereed)
    Abstract [en]

    This study investigates the corrosion resistance of two-layer Gd2Zr2O7/YSZ, three-layer dense Gd2Zr2O7/ Gd2Zr2O7/YSZ, and a reference single-layer YSZ coating with a similar overall top coat thickness of 300-320 µm. All the coatings were manufactured by suspension plasma spraying resulting in a columnar structure except for the dense layer. Corrosion tests were conducted at 900 °C for 8 h using V2O5 and Na2SO4 as corrosive salts at a concentration of approximately 4 mg/cm2. SEM investigations after the corrosion tests show that Gd2Zr2O7-based coatings exhibited lower reactivity with the corrosive salts and the formation of gadolinium vanadate (GdVO4), accompanied by the phase transformation of zirconia was observed. It is believed that the GdVO4 formation between the columns reduced the strain tolerance of the coating and also due to the fact that Gd2Zr2O7 has a lower fracture toughness value made it more susceptible to corrosion-induced damage. Furthermore, the presence of a relatively dense layer of Gd2Zr2O7 on the top did not improve in reducing the corrosion-induced damage. For the reference YSZ coating, the observed corrosion-induced damage was lower probably due to combination of more limited salt penetration, the SPS microstructure and superior fracture toughness of YSZ.

  • 46.
    Li, C.
    et al.
    University of Manchester , School of Materials, Manchester M13 9PL, UK..
    Jacques, S. D.
    University of Manchester , School of Materials, Manchester M13 9PL, UK..
    Chen, Y.
    University of Manchester , School of Materials, Manchester M13 9PL, UK..
    Daisenberger, D.
    University of Manchester , School of Materials, Manchester M13 9PL, UK..
    Xiao, P.
    University of Manchester , School of Materials, Manchester M13 9PL, UK..
    Markocsan, Nicolaie
    University West, Department of Engineering Science, Division of Subtractive and Additive Manufacturing.
    Nylén, Per
    University West, Department of Engineering Science, Division of Subtractive and Additive Manufacturing.
    Cernik, R. J.
    University of Manchester , School of Materials, Manchester M13 9PL, UK..
    A synchrotron X-ray diffraction deconvolution method for the measurement of residual stress in thermal barrier coatings as a function of depth2016In: Journal of applied crystallography, ISSN 0021-8898, E-ISSN 1600-5767, Vol. 49, no Pt 6, p. 1904-1911Article in journal (Refereed)
    Abstract [en]

    The average residual stress distribution as a function of depth in an air plasma-sprayed yttria stabilized zirconia top coat used in thermal barrier coating (TBC) systems was measured using synchrotron radiation X-ray diffraction in reflection geometry on station I15 at Diamond Light Source, UK, employing a series of incidence angles. The stress values were calculated from data deconvoluted from diffraction patterns collected at increasing depths. The stress was found to be compressive through the thickness of the TBC and a fluctuation in the trend of the stress profile was indicated in some samples. Typically this fluctuation was observed to increase from the surface to the middle of the coating, decrease a little and then increase again towards the interface. The stress at the interface region was observed to be around 300 MPa, which agrees well with the reported values. The trend of the observed residual stress was found to be related to the crack distribution in the samples, in particular a large crack propagating from the middle of the coating. The method shows promise for the development of a nondestructive test for as-manufactured samples.

  • 47.
    Li, C.
    et al.
    University of Manchester, School of Materials, M13 9PL, UK.
    Jacques, S. D. M.
    University of Manchester, School of Materials, M13 9PL, UK.
    Chen, Y.
    University of Manchester, School of Materials, M13 9PL, UK.
    Xiao, Ping
    University of Manchester, School of Materials, M13 9PL, UK.
    Beale, A. M.
    University College London, RCaH Rutherford Appleton Laboratory, Harwell Oxford Didcot Oxon, OX11 0FA, UK.
    di Michiel, M.
    ESRF-The European Synchrotron, 71, Avenue des Martyrs, Grenoble, France.
    Markocsan, Nicolaie
    University West, Department of Engineering Science, Division of Manufacturing Processes.
    Nylén, Per
    University West, Department of Engineering Science, Division of Production Engineering.
    Cernik, R. J.
    University of Manchester, School of Materials, M13 9PL, UK.
    Precise strain profile measurement as a function of depth in thermal barrier coatings using high energy synchrotron X-rays2016In: Scripta Materialia, ISSN 1359-6462, E-ISSN 1872-8456, Vol. 113, p. 122-126Article in journal (Refereed)
    Abstract [en]

    We have developed a method of directly measuring the strain gradient as a function of depth in plasma sprayed Thermal Barrier Coatings (TBCs). A 92.8 keV monochromatic synchrotron X-ray beam was used to penetrate the 10 × 10 × 8 mm samples in transmission geometry. The samples had been heated to 1150 °C and held at that temperature for 190 h. The diffraction patterns were collected using a DECTRIS pilatus3 X CdTe 300 K area detector. The patterns were analyzed by partial circular integration followed by full Rietveld refinement to obtain the lattice parameters of the TBC top coat at 25 μm intervals as function of depth. The coatings surviving the heat treatment process without significant damage were found to exhibit a variable compressive stress state inside the top coat. This was found to be about − 600 MPa at the bond coat interface decreasing in a non-linear fashion towards the surface. By refinement of the data collected from sectors of whole Debye Scherrer rings we were able to estimate both the in-plane and out-of-plane strain.

  • 48.
    Li, Peigang
    et al.
    University West, Department of Engineering Science, Division of Production Engineering.
    Nylén, Per
    University West, Department of Engineering Science, Division of Production Engineering.
    Markocsan, Nicolaie
    University West, Department of Engineering Science, Division of Production Engineering.
    Klement, Uta
    University West, Department of Engineering Science.
    Characterization of Cold Lap Defects in Tandem Arc MAG Welding2010In: Proceedings of the International Conference on Advances in Welding Science & Technology for Construction, Energy & Transportation AWST-2010: Istanbul, Turkey, 12-15 July, 2010, 2010, p. 303-311Conference paper (Refereed)
  • 49.
    Li, Peigang
    et al.
    University West, Department of Engineering Science.
    Svensson, Lars-Erik
    University West, Department of Engineering Science, Division of Production Engineering.
    Markocsan, Nicolaie
    University West, Department of Engineering Science, Division of Production Engineering.
    Factors influencing fusion of spatter to the base metal during tandem GMAW2012In: Proceedings of The 5th International Swedish Production Symposium: 6th-8th of November 2012 Linköping, Sweden / [ed] Mats Björkman, Linköping, Sweden, 2012, p. 233-239Conference paper (Refereed)
    Abstract [en]

    Tandem gas metal arc welding (tandem GMAW) is, as a high productivity welding method of manufacturing process, utilized broadly in modern Swedish industry. Spatter is more or less an inevitable flaw in GMAW, especially for the high efficiency processes. Recently, spatter was found as a potential source of cold laps, which negatively influences fatigue life. The main objectives of this paper are to investigate the spatter/base metal interface and identify the primary factors for formation of cold laps.

    Tandem GMAW was performed in a sealed chamber filled with either pure argon or pure dioxide. Cross sections of spatter and base metal were prepared and evaluated by Light optical microscopy and Scanning Electron Microscopy (SEM) with an attached Energy Dispersive Spectroscope (EDS).

    Mn-Si oxides were found to enhance the lack of fusion occurrence in the spatter/base metal. The oxide of Mn and Si mostly came from oxidation of the droplets in the welding process. Spatter diameter and spatter distance was evaluated with respect to lack of fusion in spatter/base metal interface for welds using pure Ar shielding gas. From this it was concluded that temperature is another important factor for lack of fusion formation in the spatter/base metal interface.

  • 50.
    Li, Peigang
    et al.
    University West, Department of Engineering Science.
    Svensson, Lars-Erik
    University West, Department of Engineering Science, Division of Production Engineering.
    Markocsan, Nicolaie
    University West, Department of Engineering Science, Division of Production Engineering.
    Factors influencing fusion on spatter to the base metal during tandem GMAW weldingArticle in journal (Refereed)
123 1 - 50 of 108
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