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Failure of Multilayer Suspension Plasma Sprayed Thermal Barrier Coatings in the Presence of Na2SO4 and NaCl at 900 °C
Linköping University, Department of Management and Engineering, Linköping, Sweden.
University West, Department of Engineering Science, Division of Subtractive and Additive Manufacturing. (PTW)ORCID iD: 0000-0003-2475-9284
Linköping University, Department of Management and Engineering, Linköping, Sweden.
Linköping University, Department of Management and Engineering, Linköping, Sweden.
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2019 (English)In: Journal of thermal spray technology (Print), ISSN 1059-9630, E-ISSN 1544-1016, Vol. 28, no 1-2, p. 212-222Article in journal (Refereed) Published
Abstract [en]

The current investigation focuses on understanding the influence of a columnar microstructure and a sealing layer on the corrosion behavior of suspension plasma sprayed thermal barrier coatings (TBCs). Two different TBC systems were studied in this work. First is a double layer made of a composite of gadolinium zirconate + yttria stabilized zirconia (YSZ) deposited on top of YSZ. Second is a triple layer made of dense gadolinium zirconate deposited on top of gadolinium zirconate + YSZ over YSZ. Cyclic corrosion tests were conducted between 25 and 900 °C with an exposure time of 8 h at 900 °C. 75 wt.% Na2SO4 + 25 wt.% NaCl were used as the corrosive salts at a concentration of 6 mg/cm2. Scanning electron microscopy analysis of the samples’ cross sections showed that severe bond coat degradation had taken place for both the TBC systems, and the extent of bond coat degradation was relatively higher in the triple-layer system. It is believed that the sealing layer in the triple-layer system reduced the number of infiltration channels for the molten salts which resulted in overflowing of the salts to the sample edges and caused damage to develop relatively more from the edge.

Place, publisher, year, edition, pages
2019. Vol. 28, no 1-2, p. 212-222
Keywords [en]
columnar microstructure, composite of gadolinium zirconate and YSZ, hot corrosion, suspension plasma spray
National Category
Manufacturing, Surface and Joining Technology
Research subject
ENGINEERING, Manufacturing and materials engineering; Production Technology
Identifiers
URN: urn:nbn:se:hv:diva-13100DOI: 10.1007/s11666-018-0780-5ISI: 000456599500019Scopus ID: 2-s2.0-85055998259OAI: oai:DiVA.org:hv-13100DiVA, id: diva2:1261017
Funder
VINNOVA
Note

First Online: 29 October 2018

This article is an invited paper selected from presentations at the 2018 International Thermal Spray Conference, held May 7-10, 2018, in Orlando, Florida, USA, and has been expanded from the original presentation.

Available from: 2018-11-06 Created: 2018-11-06 Last updated: 2019-02-12Bibliographically approved

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Mahade, Satyapal

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