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The Effect of Fuel Electrode Roughness on the Properties of Plasma Sprayed Solid Oxide Cells
University of Toronto, Department of Mechanical and Industrial Engineering, Toronto, Ontario M5S 3G8, Canada.
University West, Department of Engineering Science, Division of Subtractive and Additive Manufacturing. (PTW)ORCID iD: 0000-0002-4201-668X
University of Toronto, Department of Mechanical and Industrial Engineering, Toronto, Ontario M5S 3G8, Canada.
University West, Department of Engineering Science, Division of Subtractive and Additive Manufacturing. (PTW)
2018 (English)In: Journal of the Electrochemical Society, ISSN 0013-4651, E-ISSN 1945-7111, Vol. 165, no 9, p. F693-F701Article in journal (Refereed) Published
Abstract [en]

Solid oxide cell electrolytes fabricated by atmospheric plasma spraying are frequently found to have considerable gas leak rates.Electrode surface roughness is known to have an influence on electrolyte leak rates. A jet of high velocity air, produced with an airknife, was aimed at the plasma plume during fuel electrode deposition to reduce the surface roughness prior to electrolyte deposition.The resulting fuel electrode masses, electrode compositions, and electrode surface roughnesses were measured for varying air knifeinlet pressures. Surface asperity populations and maximum heights were significantly reduced using air knife pressures of >6 barat the expense of deposition efficiency. The nickel volume fraction in the fuel electrode increased slightly with increasing air knifepressure. Open circuit voltages were larger on the smoother fuel electrodes that were produced at higher air knife pressures, but nosignificant effect of air knife pressure on cell power density could be discerned.© 2018 The Electrochemical Society

Place, publisher, year, edition, pages
2018. Vol. 165, no 9, p. F693-F701
Keywords [en]
air knife, solid oxide cell, surface roughness
National Category
Manufacturing, Surface and Joining Technology Other Chemical Engineering
Research subject
ENGINEERING, Manufacturing and materials engineering; Production Technology
Identifiers
URN: urn:nbn:se:hv:diva-13050DOI: 10.1149/2.1141809jesScopus ID: 2-s2.0-85049345029OAI: oai:DiVA.org:hv-13050DiVA, id: diva2:1259259
Note

Funders: Natural Sciences and Engineering Research Council of Canada

Available from: 2018-10-29 Created: 2018-10-29 Last updated: 2019-05-28Bibliographically approved

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Gupta, Mohit KumarBjörklund, Stefan

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