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Effect of SiO2 Dispersion on Chlorine-Induced High-Temperature Corrosion of High-Velocity Air-Fuel Sprayed NiCrMo Coating
University West, Department of Engineering Science, Division of Subtractive and Additive Manufacturing. (PTW)ORCID iD: 0000-0002-7663-9631
University West, Department of Engineering Science, Division of Subtractive and Additive Manufacturing. (PTW)ORCID iD: 0000-0002-9578-4076
Univ Nottingham, Fac Engn, Nottingham NG7 2RD, England.
MH Engn AB, S-69142 Karlskoga, Sweden.
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2018 (English)In: Corrosion, ISSN 0010-9312, E-ISSN 1938-159X, Vol. 74, no 9, p. 984-1000Article in journal (Refereed) Published
Abstract [en]

NiCrMo coatings with and without dispersed SiO2 were deposited using high-velocity air-fuel technique. Thermogravimetric experiments were conducted in 5% O-2 + 500 vppm HCl + N-2 with and without a KCl deposit at 600 degrees C for up to 168 h. The SiO2-containing coating showed lower weight change as a result of formation of a protective and adherent Cr-rich oxide scale. SiO2 decelerated short-circuit diffusion of Cr3+ through scale's defects, e.g., vacancies, and promoted the selective oxidation of Cr to form the protective Cr-rich oxide scale. Furthermore, the presence of SiO2 led to less subsurface depletion of Cr in the coating, and accordingly less corrosion of the substrate. The formed corrosion product on the SiO2-free coating was highly porous, non-adherent, and thick.

Place, publisher, year, edition, pages
2018. Vol. 74, no 9, p. 984-1000
Keywords [en]
Thermal Spray Coating, Chlorine-Induced High Temperature Corrosion, NiCrMo, SiO2Dispersion, HighVelocity Air-Fuel (HVAF), Biomass-/Waste-Fired Boiler
National Category
Manufacturing, Surface and Joining Technology
Research subject
ENGINEERING, Manufacturing and materials engineering; Production Technology
Identifiers
URN: urn:nbn:se:hv:diva-12903DOI: 10.5006/2802ISI: 000442637200005Scopus ID: 2-s2.0-85052839267OAI: oai:DiVA.org:hv-12903DiVA, id: diva2:1248075
Funder
Knowledge Foundation, RUN 20160201Region Västra Götaland, RUN 2016-01489
Note

Published Online: April 24, 2018

Available from: 2018-09-13 Created: 2018-09-13 Last updated: 2019-05-28Bibliographically approved

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Sadeghimeresht, EsmaeilMarkocsan, NicolaieJoshi, Shrikant V.

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