This thesis presents the approach of determining the machining  errors on a five axis CNC machine using sensors already fitted in the machine to extract valuable data up on process called CITE(CNC Integrity Tracing Equipment) system and measuring the machined workpiece geometry using CMM(Coordinate measurement machine). CITE measurement system is the data acquisition hardware and software system developed by University West for collecting position information from encoders of a machine tool. The collected information could then be used to assess the quality and adjustment of a machine tool, CNC programs and the CNC control parameters. The aim of this study is to examine the roundness and concentricity detection capacity of the CITE system by conducting different milling methods and a turning process. In an example cutting of a workpiece, the CITE measurement system was used for recording the machining process. After that, radial error, centre point deviation and circle roundness errors, analysed using MATLAB based on collected CNC tool movement data. CMM measurement used to verify the results obtained from the CITE measurement system. The investigation conducted on the small circles shows that the CITE measurement system have capability of identifying radial errors in different method of millings (slot, up and down). Centre point deviation and roundness errors measured by the CITE system doesn`t show significant differences between milling methods as seen on CMM measurement.