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Isothermal oxidation of HVAF-sprayed Ni-based chromia, alumina and mixed-oxide scale forming coatings in ambient air
University West, Department of Engineering Science, Division of Subtractive and Additive Manufacturing.ORCID iD: 0000-0002-7663-9631
University West, Department of Engineering Science, Division of Subtractive and Additive Manufacturing. (PTW)ORCID iD: 0000-0002-9578-4076
M. H. Engineering AB, 691 42 Karlskoga, Sweden.
University West, Department of Engineering Science, Research Enviroment Production Technology West.ORCID iD: 0000-0001-5521-6894
2017 (English)In: Surface & Coatings Technology, ISSN 0257-8972, E-ISSN 1879-3347, Vol. 316, 10-21 p.Article in journal (Refereed) Published
Abstract [en]

The power generation industry has been progressively shifting towards higher operating steam temperatures and pressures to increase efficiency and reduce CO2 emissions. However, higher operating temperatures lead to more aggressive oxidation of the boiler components. A promising route to improve the durability of degradation-prone components is through deployment of high-performance coatings. In the present work, four Ni-based coatings - Ni21Cr, Ni5Al, Ni21Cr9Mo, and Ni21Cr7Al1Y - thermally sprayed by the high-velocity air fuel (HVAF) technique on boiler steel (16Mo3) substrates were investigated. The isothermal oxidation behavior of the coatings was studied in ambient air environment at 600 °C for different time intervals i.e. 1, 5, 10, 24, 48, 96, and 168 h. The oxidation behavior of the as-sprayed and polished coatings was compared. The protective α-Al2O3 was not detected on the exposed alumina-forming NiAl coating. On the other hand, Cr2O3 along with a small amount of NiO were the main oxidation products on the surface of the NiCr and NiCrMo coatings, and were found to be relatively less protective. The mixed-oxide scale forming NiCrAlY coatings showed the best oxidation resistance due to the formation of a thin and slow-growing Al2O3 scale along with Ni(Al,Cr)2O4 and Cr2O3. The polished coatings were found to significantly reduce the oxidation rate in each case as the protective scale-forming elements were more uniformly supplied to the surface oxide scale by removing the surface asperities. © 2017 Elsevier B.V.

Place, publisher, year, edition, pages
Elsevier B.V. , 2017. Vol. 316, 10-21 p.
Keyword [en]
Air; Aluminum; Aluminum coatings; Black coatings; Boilers; Carbon dioxide; Coatings; Inorganic coatings; Isotherms; Nickel; Oxidation; Scale (deposits); Sprayed coatings; Thermal spraying, High performance coatings; High velocity air fuels; Isothermal oxidations; Ni-based coatings; Operating temperature; Oxidation behaviors; Power generation industries; Scale-forming elements, Alumina
National Category
Manufacturing, Surface and Joining Technology
Research subject
ENGINEERING, Manufacturing and materials engineering
Identifiers
URN: urn:nbn:se:hv:diva-10902DOI: 10.1016/j.surfcoat.2017.03.017ISI: 000401207700002Scopus ID: 2-s2.0-85014899098OAI: oai:DiVA.org:hv-10902DiVA: diva2:1136152
Funder
Region Västra Götaland, RUN 2016-01489
Note

Projekt PROSAM

Available from: 2017-08-25 Created: 2017-08-25 Last updated: 2017-12-29Bibliographically approved

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Sadeghimeresht, EsmaeilMarkocsan, NicolaieJoshi, Shrikant V.

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