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Erosion Behavior of Gadolinium Zirconate/YSZ Multi-Layered Thermal Barrier Coatings Deposited by Suspension Plasma Spray
Högskolan Väst, Institutionen för ingenjörsvetenskap, Avdelningen för avverkande och additativa tillverkningsprocesser (AAT). (PTW)ORCID-id: 0000-0003-2475-9284
Högskolan Väst, Institutionen för ingenjörsvetenskap, Avd för maskinteknik. (PTW)
Högskolan Väst, Institutionen för ingenjörsvetenskap, Avd för tillverkningsprocesser. (PTW)ORCID-id: 0000-0002-9578-4076
Högskolan Väst, Institutionen för ingenjörsvetenskap, Avd för tillverkningsprocesser. (PTW)ORCID-id: 0000-0003-0209-1332
Visa övriga samt affilieringar
2016 (Engelska)Ingår i: Proceedings of the International Thermal Spray Conference, 2016, s. 343-347Konferensbidrag, Publicerat paper (Refereegranskat)
Abstract [en]

Yttria stabilized zirconia (8YSZ) is the standard ceramic material for thermal barrier coating (TBC)applications. However, above 1200º C, it has limitations such as poor sintering resistance & susceptibility to CMAS(Calcium Magnesium Alumino Silicates) degradation. Gadolinium zirconate (GZ) is considered as one of the promising top coat candidates for TBC applications at high temperature (>1200 ºC) due to its lower thermal conductivity, good sintering resistance and CMAS infiltration resistance. Single layer 8YSZ, double layer GZ/YSZand triple layer GZdense/GZ/YSZ TBCs were deposited by suspension plasma spray (SPS). Microstructuralanalysis was carried out by SEM (scanning electron microscopy). Phase analysis of as sprayed TBCs was carriedout using XRD (X ray diffraction). The as sprayed multi-layered TBCs were subjected to erosion test at room temperature and their erosion resistance was compared with single layer 8YSZ. It was observed that the erosion resistance of 8YSZ TBC was higher than GZ/YSZ multi-layered TBCs at room temperature. Among the multilayered TBCs, triple layer TBC was slightly better than double layer in terms of erosion resistance.

Ort, förlag, år, upplaga, sidor
2016. s. 343-347
Nyckelord [en]
Thermal barrier coating
Nationell ämneskategori
Bearbetnings-, yt- och fogningsteknik
Forskningsämne
Produktionsteknik
Identifikatorer
URN: urn:nbn:se:hv:diva-9856Scopus ID: 2-s2.0-85026871726OAI: oai:DiVA.org:hv-9856DiVA, id: diva2:957993
Konferens
International Thermal Spray Conference, May 10-12, 2016, Shanghai, DVS Media
Tillgänglig från: 2016-09-05 Skapad: 2016-09-05 Senast uppdaterad: 2019-02-07Bibliografiskt granskad
Ingår i avhandling
1. Functional Performance of Gadolinium Zirconate/Yttria Stabilized Zirconia Multi-Layered Thermal Barrier Coatings
Öppna denna publikation i ny flik eller fönster >>Functional Performance of Gadolinium Zirconate/Yttria Stabilized Zirconia Multi-Layered Thermal Barrier Coatings
2016 (Engelska)Licentiatavhandling, sammanläggning (Övrigt vetenskapligt)
Abstract [en]

Yttria stabilized zirconia (YSZ) is the state of the art ceramic top coat material used for TBC applications. The desire to achieve a higher engine efficiency of agas turbine engine by increasing the turbine inlet temperature has pushed YSZ toits upper limit. Above 1200°C, issues such as poor phase stability, high sinteringrates, and susceptibility to CMAS (calcium magnesium alumino silicates) degradation have been reported for YSZ based TBCs. Among the new materials,gadolinium zirconate (GZ) is an interesting alternative since it has shown attractive properties including resistance to CMAS attack. However, GZ has a poor thermo-chemical compatibility with the thermally grown oxide leading to poor thermal cyclic performance of GZ TBCs and that is why a multi-layered coating design seems feasible.This work presents a new approach of depositing GZ/YSZ multi-layered TBCs by the suspension plasma spray (SPS) process. Single layer YSZ TBCs were also deposited by SPS and used as a reference.The primary aim of the work was to compare the thermal conductivity and thermal cyclic life of the two coating designs. Thermal diffusivity of the YSZ single layer and GZ based multi-layered TBCs was measured using laser flash analysis (LFA). Thermal cyclic life of as sprayed coatings was evaluated at 1100°C, 1200°C and 1300°C respectively. It was shown that GZ based multi-layered TBCs had a lower thermal conductivity and higher thermal cyclic life compared to the single layer YSZ at all test temperatures. The second aim was to investigate the isothermal oxidation behaviour and erosion resistance of the two coating designs. The as sprayed TBCs were subjected toisothermal oxidation test at 1150°C. The GZ based multi-layered TBCs showed a lower weight gain than the single layer YSZ TBC. However, in the erosion test,the GZ based TBCs showed lower erosion resistance compared to the YSZ singlelayer TBC. In this work, it was shown that SPS is a promising production technique and that GZ is a promising material for TBCs.

Ort, förlag, år, upplaga, sidor
Trollhättan: University West, 2016. s. 70
Serie
Licentiate Thesis: University West ; 11
Nyckelord
Erosion, Gadolinium Zirconate, Suspension Plasma Spray, Thermal Barrier Coatings, Thermal Cyclic Test, Thermal Conductivity, Yttria Stabilized Zirconia
Nationell ämneskategori
Bearbetnings-, yt- och fogningsteknik
Forskningsämne
Produktionsteknik
Identifikatorer
urn:nbn:se:hv:diva-9854 (URN)978-91-87531-36-1 (ISBN)978-91-87531-37-8 (ISBN)
Externt samarbete:
Handledare
Tillgänglig från: 2016-09-09 Skapad: 2016-09-05 Senast uppdaterad: 2016-09-06Bibliografiskt granskad

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